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Orgo II Tutorial: Introduction to Enols & Enolates
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\({\bf{Enol~Structure~and~pKa:}}\) |dw:1542067733795:dw|
|dw:1542067857799:dw|
\({\bf{Tautomerization:}}\) |dw:1542068076908:dw|
with one practical exception, the keto form tends to form more readily due to the stability of the C=O bond. as the level of substitution on the double bond increases, the enol form becomes more favored. one notable form happens when dicarbonyl compound is converted to enol form; the enol form appears with 76% composition due to the cyclical intermediate formed when the carbonyl is protonated |dw:1542068612359:dw|
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Anyway, that's the end of my tutorial, I hope it was a helpful resource. Source material is Organic Chemistry 12th edition by Solomons, et. al.
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