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Samuel de Champlain led the first successful French settlement in Canada at: Montreal Quebec New France
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According to the Mariner's Museum, "during [Samuel's] travels, he mapped the Atlantic coast of Canada, parts of the St. Lawrence River, and parts of the Great Lakes. He is best known for establishing the first French settlement in the Canadian territory, and founding the city of Quebec. Because of this, Champlain became known as the “Father of New France.”"
So the answer would be Quebec.
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