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OpenStudy (anonymous):
NCl5 do not exist but PCl5 does.. why??
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OpenStudy (jfraser):
phosphorus can use its nearby d-orbitals and hybridize them to accept up to 12 electrons in its outer level, meaning up to 6 bonds. Nitrogen has no nearby d-orbitals, so it's stuck with a maximum of 4 bonds.
OpenStudy (chmvijay):
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