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Chemistry 11 Online
OpenStudy (king):

Balance the charges and masses in foll. equation: I shall post equations in reply Pls help wid explanantion !!

OpenStudy (king):

\[CuS + NO _{3}^{-} --> Cu ^{2+}+ \S _{8}+NO\]

OpenStudy (king):

sry thats S8 in the product side

OpenStudy (anonymous):

re u sure equation i correct as if u see in the reaction O is not balanced first try to balance it

OpenStudy (king):

no my sir said that fr O we should balance using H20 and then add H+ ion to reactant side to balance H...oh yeah this is a acid base reaction

OpenStudy (anonymous):

hey is thiss redox reaction? right in which medium u have to do balancing?

OpenStudy (anonymous):

i mean acidic medium or basic medium u are provided this info?

OpenStudy (king):

acidic medium

OpenStudy (anonymous):

ok so first write down half oxidation and half reduction reaction if u are having problem in this step say ok i ll help u

OpenStudy (king):

i dont understand hw to do this prob.if u could explain i could try the remaining..as fr the prob i know that Copper loses 2 e- and i am not sure if Nitrogen loses 1 e- or gains 5 e- bcuz N oxidation state is +5 in reactant side

OpenStudy (anonymous):

u know NO3- here it charge is +5 and in product ide NO its charge is -2 means from being +5 to -2 is reduction right means its half reduction reaction

OpenStudy (king):

in NO charge is 0

OpenStudy (king):

haan mujhe hindi pata he

OpenStudy (king):

u der?

OpenStudy (anonymous):

rry actauly O have -2 charge always wid it ok its not evrytime gonna shown u

OpenStudy (king):

oh ok!

OpenStudy (king):

wat abt remaining can u do this 1 fr me wid steps so i can apply and do fr my other 2

OpenStudy (king):

and in NO N charge is +2 not -2 so its oxidation

OpenStudy (anonymous):

ok now see half reduction reaction half oxidation reaction NO3- -------------> NO CuS----------------S8 +5 ---------------> +2 -2--------->0 [charge]

OpenStudy (anonymous):

get this much ?

OpenStudy (king):

ok i got it!thnk!

OpenStudy (anonymous):

now we will balance NO3- -------------> NO H+ + NO3 -----------> NO + H2O ( by adding water balance this equation)

OpenStudy (king):

ok luk at this prob i noted down oxidation and reduction reactions but still its coming wrong

OpenStudy (king):

i got the 1st one

OpenStudy (king):

\[Cr _{2}O _{7^{2-}}+I ^{-} -->Cr ^{3+}+I _{2}\]

OpenStudy (king):

i multiply I by 2 in reactant side,and Cr by 2 in product side first

OpenStudy (anonymous):

first u say den i ll solve

OpenStudy (king):

then i find that Cr undergoes reduction by gaining 3 e- as it is +6->+3 and I undergoes oxidation by losing 2 e- +2->0

OpenStudy (king):

so i cross multiply and get 28H+ + 2Cr2O7- + 6I- --->4Cr3+ +3I2 + 14H20

OpenStudy (king):

but charges are not balanced so what to do?

OpenStudy (king):

@heena u der?

OpenStudy (anonymous):

give me a sec

OpenStudy (king):

kk

OpenStudy (anonymous):

srry wait

OpenStudy (anonymous):

i m gettin 14H+ + cr2o7-2----------------> 2Cr3+ + 7/2H2O + 15e-

OpenStudy (king):

if u put 7/2 H20 then masses are not balanced

OpenStudy (king):

and in ure equation charges are not balanced

OpenStudy (anonymous):

wen u do blcing in equtaion masses dont make any effect ok only mole volume dey do so

OpenStudy (king):

no but my sir wants masses and chrges both balanced

OpenStudy (anonymous):

iabove eqn is wrong 7H+ + cr2o7-2----------------> 2Cr3+ + 7/2H2O + 8e- +5 -5 the only prob is sigm is different in charge :(

OpenStudy (callisto):

Hello :)

OpenStudy (anonymous):

ok u done this with ion electron method

OpenStudy (callisto):

Eh... It's based on change in oxidation number..

OpenStudy (anonymous):

but the way d way i m doing here wats troubling here @callistion can u guide?

OpenStudy (callisto):

+6, -1, +3, 0 are oxidation numbers.. and one marked with pencil is the change

OpenStudy (anonymous):

yea i get that thing wat u done but i m thig wat i have done wrong here (:

OpenStudy (callisto):

gimme some time to write , please?

OpenStudy (anonymous):

anyway i ll do dis qn later hope callisto will guide u in above problem @king bye

OpenStudy (king):

@heena bye@callisto thnx a lot and bye!

OpenStudy (callisto):

People are leaving.. :(

OpenStudy (callisto):

Do you understand...?

OpenStudy (anonymous):

y u upsad ? dont worry i m still here :)

OpenStudy (callisto):

Good :) Do you understand?

OpenStudy (anonymous):

yes mam :)

OpenStudy (callisto):

Great! and my mission's completed?

OpenStudy (anonymous):

:) are u good in bio i need help?

OpenStudy (callisto):

i don't study Biology, sorry :(

OpenStudy (anonymous):

no prob :) u knw hydrocarbon?

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