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Chemistry 18 Online
OpenStudy (anonymous):

balance the following redox reaction : TlO3 + NH2OH----->TlOH+N2 can someone please explain this tooo me. I got to elements thats are reduced. :(

OpenStudy (aaronq):

do you know how to assign oxidation states?

OpenStudy (anonymous):

yes you mean oxidation numbers

OpenStudy (aaronq):

haha yeah thats what i mean. Are you balancing by a certain method? i only know the half reaction method

OpenStudy (anonymous):

yes that one . AND IM CLUELESS , i thought i gripped the concept but now im lost !!!!

OpenStudy (aaronq):

so you assigned oxidation numbers to everything? what did you get?

OpenStudy (anonymous):

for Tl i got -3 O3 = -2 N=-1 H2= 1 O= -2 H=1 thoses are the reactants the products i got Tl = 1 O= -2 H= 1 N2= 0 is that right ???

OpenStudy (aaronq):

oh god why would you write it like that.. (+6)(-6) (-1)(+2)(-2)(+1) (+1)(-2)(+1) 0 TlO3 + NH2OH-----> TlOH + N2 so you got the TlO3 wrong

OpenStudy (anonymous):

sorrry :(

OpenStudy (aaronq):

haha it's cool, it's just more confusing

OpenStudy (anonymous):

i couldnt think of another way Lol i was caught up in this problem

OpenStudy (aaronq):

Sorry it should be like this: (+6)(-2) (-1)(+1)(-2)(+1) (+1)(-2)(+1) 0 TlO3 + NH2OH-----> TlOH + N2

OpenStudy (anonymous):

ok , ok iget it so Tl is oxided and N is reduced right

OpenStudy (anonymous):

thank you soo much

OpenStudy (anonymous):

wait im soo sorry it should be Tl2 for the reactants

OpenStudy (anonymous):

im soo sorrry its my fault i forget the 2 when i typed it

OpenStudy (aaronq):

it's actually the other way around.. Tl (+6) -> Tl (+1) N (-1) -> N (0)

OpenStudy (anonymous):

ok im soo smart lol

OpenStudy (aaronq):

reduction is the gain of electrons.. meaning going more negative

OpenStudy (aaronq):

haha getting there !

OpenStudy (anonymous):

hehhe what are you implieing im dumb! lol

OpenStudy (aaronq):

haha nono okay so you're saying it should be Tl2?

OpenStudy (anonymous):

yes

OpenStudy (anonymous):

i was only joking btw

OpenStudy (aaronq):

lol same here... (+3)(-2) (-1)(+1)(-2)(+1) (+1)(-2)(+1) 0 Tl2O3 + NH2OH-----> TlOH + N2 like that?

OpenStudy (aaronq):

do you know what to do next?

OpenStudy (anonymous):

ok then u write the half life of the ones that are oxided and reduced

OpenStudy (aaronq):

and you balance the number of electrons transferred

OpenStudy (aaronq):

is this in acidic or basic medium?

OpenStudy (anonymous):

yes its basic ?

OpenStudy (aaronq):

so once you balance the number of electrons balance the charges with OH- then balance the number of O's and H's with H2O

OpenStudy (aaronq):

capiche?

OpenStudy (anonymous):

for Tl2 i made it negative instead of positive , that why i got to reduced elements

OpenStudy (anonymous):

capiche my friend :)

OpenStudy (aaronq):

ohh okay, well at least you got where you went wrong. if you get stuck again, just ask !

OpenStudy (anonymous):

dont worry i wont hestatiate to ask. Ur soo nice

OpenStudy (anonymous):

listen i hate ap chem and im pretty sure i will have tons of questions lol

OpenStudy (aaronq):

haha okok

OpenStudy (anonymous):

ok ok

OpenStudy (anonymous):

thanks again

OpenStudy (aaronq):

yeah no problem, i actually found these fun when i had to do them haha

OpenStudy (anonymous):

lucky you !!! unlike me , so i assume ur out of college

OpenStudy (anonymous):

or in college

OpenStudy (aaronq):

i'm in 2nd year, had to do them last year

OpenStudy (anonymous):

oh nice well good luck

OpenStudy (aaronq):

thanks, good luck to you as well !

OpenStudy (anonymous):

thank you :)

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