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Chemistry 19 Online
OpenStudy (anonymous):

Cr2O72- (aq) + NO2- (aq) --> Cr3+ (aq) + NO3- (aq) What is the reducing agent in this reaction?

OpenStudy (anonymous):

NO2-?

OpenStudy (cyber405):

Yes...Do you know why..?

OpenStudy (anonymous):

Well, I worked it out that Cr2O72- was reduced from 2- to 3+. So, it must have been reduced by the NO2-. Is my reasoning right?

OpenStudy (cyber405):

OpenStudy (cyber405):

Cr(VI) ---> Cr(III) N(III) ---> N(V)

OpenStudy (anonymous):

I am wrong.

OpenStudy (cyber405):

Why?

OpenStudy (anonymous):

Because Cr2O72- is oxidized.

OpenStudy (anonymous):

I am very confused now...

OpenStudy (cyber405):

Cr2O7(2-) + 6e ---> 2Cr(3+) NO2(-) ---->NO3(-) + 2e Ok..? What's the problem?

OpenStudy (anonymous):

So what has been reduced then?

OpenStudy (cyber405):

Reduction means receiving electron and Oxidation means giving electron... Here Cr is reduced...

OpenStudy (anonymous):

So, Cr2O72- has lost electrons hasn't it?

OpenStudy (cyber405):

No Cr2O7(2-) has received electron... Cr2O7(2-) + 14H(+) + 6e- >> 2Cr(3+) + 7H2O Do you know how to calculate oxidation number...?

OpenStudy (anonymous):

So Cr2O72- is reduced, and No2- is oxidized? And No2- is the reducing agent?

OpenStudy (cyber405):

That's right man...:)

OpenStudy (anonymous):

okay :)

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