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OpenStudy (anonymous):
Cr2O72- (aq) + NO2- (aq) --> Cr3+ (aq) + NO3- (aq)
What is the reducing agent in this reaction?
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OpenStudy (anonymous):
NO2-?
OpenStudy (cyber405):
Yes...Do you know why..?
OpenStudy (anonymous):
Well, I worked it out that Cr2O72- was reduced from 2- to 3+. So, it must have been reduced by the NO2-. Is my reasoning right?
OpenStudy (cyber405):
OpenStudy (cyber405):
Cr(VI) ---> Cr(III)
N(III) ---> N(V)
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OpenStudy (anonymous):
I am wrong.
OpenStudy (cyber405):
Why?
OpenStudy (anonymous):
Because Cr2O72- is oxidized.
OpenStudy (anonymous):
I am very confused now...
OpenStudy (cyber405):
Cr2O7(2-) + 6e ---> 2Cr(3+)
NO2(-) ---->NO3(-) + 2e
Ok..?
What's the problem?
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OpenStudy (anonymous):
So what has been reduced then?
OpenStudy (cyber405):
Reduction means receiving electron and Oxidation means giving electron...
Here Cr is reduced...
OpenStudy (anonymous):
So, Cr2O72- has lost electrons hasn't it?
OpenStudy (cyber405):
No Cr2O7(2-) has received electron...
Cr2O7(2-) + 14H(+) + 6e- >> 2Cr(3+) + 7H2O
Do you know how to calculate oxidation number...?
OpenStudy (anonymous):
So Cr2O72- is reduced, and No2- is oxidized? And No2- is the reducing agent?
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OpenStudy (cyber405):
That's right man...:)
OpenStudy (anonymous):
okay :)
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