3. Given the following equations, calculate the ΔH of reaction in which sulfur dioxide (SO2) is reduced by hydrogen disulfide (H2S) to give elemental sulfur and water (H2O).
We are given the enthalpy of formation of 3 compounds; sulfur dioxide (SO₂), water (H₂O) and hydrogen sulfide (H₂S): (we need to flip the second reaction) H₂ (g) + S (s) → H₂S (g) ΔH = -20.6 kJ S (s) + O₂ (g) → SO₂ (g) ΔH = -296.8 kJ H₂ (g) + O₂ (g) → H₂O (g) ΔH = -285.8 kJ We are asked to find the enthalpy for the following reaction: SO₂ (g) + 2H₂S (g) → 3S (s) + 2H₂O (g) Recall that ΔH of a reaction is (n and m are the coefficients of the species): m(Σ ΔH formation of products) - n(Σ ΔH formation of reactants) In our case: ΔH = [3*ΔH of S(s) + 2*ΔH of H₂O(g)] - [2*ΔH of H₂S + ΔH of SO₂] = [3*0 kJ + 2*(-285.8 kJ)] - [2*(-20.6 kJ) + (-296.8 kJ)] Source: http://au.answers.yahoo.com/question/index?qid=20130410152319AArYL5Y
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