A sample of a volatile liquid is vaporized completely in a 240.0 cm3 flask at 99°C and 757 mm Hg. The condensed vapor weighs 0.465 g.
What is the molar mass of the liquid?
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OpenStudy (zpupster):
PV=nRt
or
n=PV/RT
n= no. of moles
now convert the units to match R's unit
R the ideal Law gas constant = 8.31 J/KT
so remember J=m^3*Pa
Pressure=(in Pa) 133.2*757mmHg =
Volume =(in m^3) = 240*10^-6 m^3=
R=8.31 J/KT
T (in K) = 99C+273 =
place this in our formula and we will have our moles = ?moles
molar mass = 0.465g./?moles
OpenStudy (anonymous):
so it's the same as the mass of the condensed vapor?
OpenStudy (joannablackwelder):
Yes. Mass is conserved.
OpenStudy (anonymous):
oh thanks you
OpenStudy (joannablackwelder):
You're welcome.
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OpenStudy (anonymous):
oh wait i was only able to do conversion at operation as of now. and i got 0.0078. hmmmm why??
OpenStudy (joannablackwelder):
Did you be careful to use consistent units with your R value?
OpenStudy (anonymous):
yes i actually tried it twice. same outcome though
OpenStudy (joannablackwelder):
I converted to Liters, Kelvin, and atm and used 0.0820574 for R. I got n=0.00783 moles. Then mass/moles gives molar mass.
OpenStudy (anonymous):
ohhh exactly the same haha. mass of what should be used? in mass/moles :)
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OpenStudy (joannablackwelder):
:) the mass given in the problem statement.
OpenStudy (anonymous):
oh right my bad haha :)
so 59.62 g/mol
OpenStudy (joannablackwelder):
Yes, that is what I get. :)
OpenStudy (anonymous):
wahha thankyou :)))
OpenStudy (joannablackwelder):
Good job. :)
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