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Chemistry 23 Online
OpenStudy (anonymous):

I need help with this enthalpy question on Hess' law (in attached photo)

OpenStudy (anonymous):

OpenStudy (abmon98):

\[Mg+2HCl \rightarrow MgCl2+H2 \] \[MgO+2HC \rightarrow MgCl2 +H2O \] \[Q=mc \Delta T\] \[Q of Reaction 1=100*4.18*(32.2-21.3) \] \[Q of reaction 2=100*4.18*(28.8-21.4)\] \[Number of Moles=Mass(g)/Molar Mass(g/mol)\] \[ number of moles of Mg-0.244/24\] \[Number of Moles=0.996/(24*1)+(16*1)\] \[\Delta H=(Q/1000)/Number of Moles\]

OpenStudy (abmon98):

Is everything clear till now @hihellohi ? :)

OpenStudy (anonymous):

Ok yes thanks again! I just thought that both trials were supposed to be combined. thanks again!

OpenStudy (anonymous):

I have one question, I was wondering where 4.18 came from?

OpenStudy (abmon98):

they are going to combine that's true, i was just making sure that everything is clear about what i have wrote. 2Mg+O2-->2MgO MgO+2HCl-->H2O+MgCl2 Mg+2HCl-->MgCl2+H2 2H2+O2-->2H2O Reverse reaction 1 H2O+MgCl2-->MgO+2HCl Mg+2HCL-->H2+MgCl2 2H2+O2-->2H2O Multiply reaction 1 and 2 by 2 2H2O+2MgCl2-->2MgO+4HCL 2Mg+4HCl-->2H2+2MgCl2 2H2+O2-->2H2O Cancel out like compounds and add Delta H 2Mg+O2-->2MgO

OpenStudy (abmon98):

i forgot something when you multiply by 2 the whole equation don't forget to multiply delta H also by 2 and when you reverse equation your reverse the sign.

OpenStudy (abmon98):

specific heat capacity of water (4.18 kJ kg-1 °C-1) if c is not provided we use the specific heat capacity of water

OpenStudy (anonymous):

thanks a lot! I understand it now!

OpenStudy (abmon98):

your most welcome good to hear that :)

OpenStudy (anonymous):

May I ask one more question? For my final answer for delta H, I got 659 KJ/mol. Should it be -659 KJ/mol? because I have to do percent error and the accepted theoretical value is -601.6 KJ/mol

OpenStudy (abmon98):

to be honest i do know about the last part.

OpenStudy (abmon98):

but if the answer is +659 KJ/mol then its +659KJ/mol

OpenStudy (anonymous):

Oh ok. I'll retry it then

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