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OpenStudy (zale101):

Mass Spectroscopy Question

OpenStudy (zale101):

OpenStudy (zale101):

@Photon336

OpenStudy (photon336):

hm Let me see

OpenStudy (photon336):

"Finding the relative formula mass (relative molecular mass) from a mass spectrum is therefore trivial. Look for the peak with the highest value for m/z, and that value is the relative formula mass of the compound."

OpenStudy (zale101):

There has to be an m/z-43 in order for the acetyline ion be present

OpenStudy (zale101):

Actually, i have a chart for the m/z of some known structures.

OpenStudy (zale101):

I will attach it below.

OpenStudy (photon336):

|dw:1457410503174:dw|

OpenStudy (photon336):

|dw:1457410870834:dw|

OpenStudy (photon336):

@Zale101 I'm wondering if you can use the m/Z values to identify the fragments on the graph, for each compound.

OpenStudy (zale101):

Ahhh, i see now. Thanks!

OpenStudy (photon336):

What I did was I figured out the molar mass of one of the compounds and matched it with the corresponding m/Z value

OpenStudy (photon336):

I'm pretty sure you can do that for the other compounds. a,b,c

OpenStudy (zale101):

What's getting me confused is having M+1, M+2...

OpenStudy (zale101):

Sorry, i was lagging.

OpenStudy (zale101):

Anyways, the mass of the radical positive ion is the m/z. M-29 or some other number is the mass of the fragment.

OpenStudy (photon336):

no problem

OpenStudy (photon336):

take a look at this http://www.chemguide.co.uk/analysis/masspec/mplus2.html

OpenStudy (photon336):

could probably get a discussion going on this, and we can work together and figure it out. I never used mass spec though. I did HPLC, H-NMR, IR,

OpenStudy (zale101):

I did NMR and IR last semester, but Mass spec is really new to me.

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