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OCW Scholar - Introduction to Solid State Chemistry
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Lecture 4, homework problem 1. The solution uses positive K.\[hc/\lambda=KZ^2/n^2+m_ev^2/2=K/9+m_ev^2/2\]\[v=9.35*10^5 m/s\] Shouldn't this be negative K?\[hc/\lambda=-KZ^2/n^2+m_ev^2/2=-K/9+m_ev^2/2\]\[v=1.39*10^6 m/s\] Is positive K used because we are talking about the energy and velocity of the free electron instead of the bound electron?
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THere I find a fishy thing too, the term that is \[\left( 1/nf ^{2} - 1/n i^{2} \right) \] is expressed just as 1/nf ^{2} I cant understand why would they skip the initial n=1
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