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Chemistry 14 Online
OpenStudy (frostbite):

Can you from a NMR diagram see how an ester is turning? (where is the biggest shielding; the hydrogens that see the carbon on the ester or the hydrogens that see the oxygen on the ester.)

OpenStudy (frostbite):

@Preetha

OpenStudy (frostbite):

H-NMR by the way.

OpenStudy (chmvijay):

what exactly you want

OpenStudy (chmvijay):

ester turning to what

OpenStudy (frostbite):

The following an example. |dw:1362586957270:dw|

OpenStudy (frostbite):

Well my question is what carbon attached to the ester group is most shielded when we do NMR?

OpenStudy (chmvijay):

hydrogen that sees the carbon more is shielded

OpenStudy (frostbite):

Why is that? I mean the oxygen is more electronegative and closer?

OpenStudy (chmvijay):

yaaa exactly right if hydrogen is near More electronegative it pulls all the electron density from H and H is less shielded

OpenStudy (frostbite):

Right. Well thank you, the master students here were unsure and said it might not even be measurable.

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