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Vocaloid:
Just need some help drawing out some of the intermediary steps in this dichlorocarbene reaction
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Vocaloid:
I am given cyclohexene, which reacts w/ KOC(CH3)3 and CHCl3 to make |dw:1529692234669:dw|
Vocaloid:
like, I think that the double bond gets attacked by CCl2 but not sure how to get to that step
MARC:
|dw:1529720201812:dw|
MARC:
|dw:1529720526112:dw|
MARC:
|dw:1529720749135:dw|
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MARC:
|dw:1529720820165:dw||dw:1529720830294:dw|
MARC:
|dw:1529721012334:dw||dw:1529721074380:dw|
MARC:
we must remove the rather acidic proton from CHCl3 to give the carbanion. This loses chloride to give dichlorocarbene and insertion into cyclohexene gives the product.
Vocaloid:
makes sense, thank you ~
MARC:
yw! ^
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