Suppose you want to synthesize a solid that is both heat resistant and a good electrical conductor. What specific types of bonding and molecular interactions would you want in your starting materials?
My answer is: You want to wind up with a material that has ionic bonding or strong covalent bonds. It should be a conductor, semi conductor or a solid electrolyte. Alternatively, you could take a conductor and give it a heat resistant coating. Does anyone have a better answer?
good thinking........ could you mention some material that has ionic bonding or strong covalent bonds.
Here are some examples of modern ceramics with ionic bonds:\[Al_2O_3 \hspace{20pt} ZrO_2 \hspace{20pt} BeO\] http://en.wikipedia.org/wiki/Alumina http://en.wikipedia.org/wiki/Zirconia http://en.wikipedia.org/wiki/Beryllia By "strong covalent bonds", I meant network covalent bonding. http://en.wikipedia.org/wiki/Network_covalent_bonding Covalent solids are 3 dimensional network arrays held together by covalent bonds. Here are a few examples: \[C\space(Diamond, \space Graphite)\hspace{20pt}SiO_2\space(Quartz) \hspace{20pt} SiC \hspace{20pt} Si_3N_4 \hspace{20pt} BN\] http://en.wikipedia.org/wiki/Diamond http://en.wikipedia.org/wiki/Graphite http://en.wikipedia.org/wiki/Quartz http://en.wikipedia.org/wiki/Silicon_carbide http://en.wikipedia.org/wiki/Silicon_nitride http://en.wikipedia.org/wiki/Boron_nitride Evidently, some ceramics have mixed covalent/ionic bonds. \[WC \hspace{20pt} TiB_2\] http://en.wikipedia.org/wiki/Tungsten_carbide http://en.wikipedia.org/wiki/Titanium_diboride I mainly focused on ceramics in my reply. Here are a couple of links to information on ceramics. http://en.wikipedia.org/wiki/Ceramic http://www.mse.kth.se/student-info/0304/4H1505/F1.pdf I have also included a powerpoint presentation I found on the net.
FYI, cubic zirconia and moissanite are used as diamond substitutes. \[ZrO_2 \hspace{20pt} SiC\] http://en.wikipedia.org/wiki/Cubic_zirconia http://en.wikipedia.org/wiki/Moissanite Ruby and Sapphire are both corundum, but they have different impurities: \[Al_2O_3\] http://en.wikipedia.org/wiki/Corundum http://en.wikipedia.org/wiki/Ruby http://en.wikipedia.org/wiki/Sapphire All of these were listed above in my previous post. Obviously, not all SiC is gemstone quality. Most is not. As far as I know, there is only one company in the world that makes gemstone quality SiC. http://www.charlesandcolvard.com/
cooooooool
among these which are conductors and which are semi conductors /solid electrolyte.
So far as I can tell, solid electrolytes are ionic crystals with voids in the crystal lattice: http://en.wikipedia.org/wiki/Fast_ion_conductor So that rules out all of the covalent network solids. I don't know enough to say, but the substances with mixed bonds might not work either. Wikipedia mentions yttria-stabilized zirconia.\[ZrO_2 \space stabilized \space with \space Y_2O_3\] http://en.wikipedia.org/wiki/Yttria-stabilized_zirconia It is interesting to note that cubic zirconia (cheap but heavy diamond substitute in jewelry) is:\[ZrO_2 \space stabilized \space with \space MgO\space or \space Y_2O_3\space or \space CaO \space or \space Ce_2O_3\] http://en.wikipedia.org/wiki/Zirconium_dioxide So yttria-stablized zirconia is a flavor of cubic zirconia, if the crystal structure is cubic. http://en.wikipedia.org/wiki/Cubic_crystal_system The problem I had with this problem is that a lot of thermal insulators are also poor conductors. Perhaps the "correct" answer is actually a metal or alloy with a high melting point. Ie, a refractory metal. http://en.wikipedia.org/wiki/Refractory_metals I think iridium, rhenium, and titanium are my favorite refractory metals. http://en.wikipedia.org/wiki/Rhenium http://en.wikipedia.org/wiki/Titanium http://en.wikipedia.org/wiki/Iridium Although platinum and palladium are not refractory metals, I like all of the platinum group metals. http://en.wikipedia.org/wiki/Platinum_group_metals
Run a cost analysis of this substance, feasibility of production/ availability/ and possible hazzards. then summerise. you will make the best answer for this question.
Thanks for the help. At this point I'm pretty confident I know what is going in this problem.
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