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what is the concentration of the oxalate ion when the first cation begins to precipitate
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What cation(s) do you have? \(Ca^{2+}\) and \(Mg^{2+}\) There's some missing information there.
sorry haha the other part is: If a solution contains 0.01 M Ca2+ and 0.01 M NI2+ ions and you want to separate them using aqueous (NH4)2C2O2, which ion will precipitate first as an oxalate, Cac2o4 or Nic2O4? Ksp CaC2O4=4.75 X 10^-4 Ksp NiC2O4=4.0 X 10^-10
Since Ksp of CaC2O4 > Ksp of NiC2O4, CaC2O4 is more soluble than NiC2O4 and Ni2+ will precipitate first.
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