If the rate of disappearance H2 = -0.13 M/s at a specific time, what is the value for the rate of formation of HCl during the same interval?
This relationships depends on the mechanism. What is the chemical equation of the reaction you are analyzing?
H2 + 2 ICl I2 + 2HCl…
Plz help me understand the concept
how will I find the value of rate?
Let's forget about rate for a second. If one mol of H2 has been reacted, how many moles of HCl is formed?
I dont know:(
2
as we can see in the product side
2HCL
That's right. Based on the coefficients, you know that each molecule (and mol) of H2 will go to form two molecules (and mol) HCl.
yes
So we can make an assumption that over any time interval, the ratio of H2 consumed to the ratio of HCl produced will be... \[H_{2_{consumed}}:HCl_{produced}=1:2\]
Let's look back at the original problem now.
yes 1:2
If the rate of disappearance of H2 is -0.13M/s:\[Rate_{H_2}=-0.13\frac{M}{s} \]That means that every second, one M of H2 is being reacted. What does 1M mean in terms of moles?
the molecule of Hydrogen
that is disappeared every second and making two molecules of HCL
So if you have twice the number of molecules disappearing over the same time interval, what is the rate of disappearance of HCl?
1 mol
\[Rate=\frac{molecules}{t}\]
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is this correct
whre as - shows the decrease in the rate of molecules
Where delta A is the number of molecules?
*Change in number of molecules.
yes
is this the right equation?
what is the time in this case?
The rate must be multiplied by the reciprocal of the stoichiometric coefficient to account for what we just discussed. For a chemical equation:\[aA+bB \rightarrow cC+dD\]Where lower case letters are stoichiometric coefficients and capital letters are some chemical species, the following is true:\[Rate_{rxn}=\frac{-1}{a}\frac{\Delta [A]}{\Delta t}=\frac{-1}{b}\frac{\Delta [B]}{\Delta t}=\frac{1}{c}\frac{\Delta [C]}{\Delta t}=\frac{1}{d}\frac{\Delta [D]}{\Delta t}\]Does that make sense? This is basically the equation you gave, except it didn't take into account the stoichiometric coefficients.
I got it . but in this question how will I find the value ?
do I have to add the values of all the reactant and product sides/
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