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Find the volume occupied by 0.5 mole of water vapour
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Just find the radius of two h atoms and one o atom and then find and their volumes together. The resultant value will be the volume of one molecule of water. Now calculate the same for 0.5 mole that is half of avogadro's number of molecules. Tis will tell you how much volume it will occupy. Remember the STP concept. Because volume of gases can be taken into account only at standard temperature and pressure (22.4 l volume is occupied by 1 mole of any substance).
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