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Chemistry 20 Online
OpenStudy (anonymous):

Which one is more acidic and why? CH3COOH or CL3CCOOH?

OpenStudy (vincent-lyon.fr):

Check which of the two conjugate bases is more stable.

OpenStudy (anonymous):

And the stronger acid would have the weaker conjugate base right?

OpenStudy (anonymous):

@Vincent-Lyon.Fr

OpenStudy (anonymous):

i would ask myself: what is the key difference between the bonding structures? then i would look up the factors that stabilize the conjugate base, like vincent-lyon said.

OpenStudy (chmvijay):

it works on inductive effect chlorine being more electronegative try to pull the negative charge of O- of acetate ions so it can liberate the H+ very easily :) hence Cl3COOH is more acidic :)

OpenStudy (vincent-lyon.fr):

Correct. The conjugate base \(CCl_3COO^-\) has its negative charge stabilised by inductive effect. Hence it is more stable than \(CH_3COO^-\), hence \(CCl_3COOH\) is a stronger acid than \(CH_3COOH\) .

OpenStudy (anonymous):

Yup thats what i thought too :) @chmvijay

OpenStudy (chmvijay):

@moni2529 thank you for that :)

OpenStudy (anonymous):

Yup @ anoop27

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