How do you find oxidation numbers?

Question

aaronq · Answer

You start off with a basic set of rules and you figure the rest out with simple arithmetic.

Rules (most often true, except in rare occasions): 
Group 1 always +1
Group 2 always +2
Oxygen always -2
Group 7 always -1
Noble gases, elemental or homonuclear (the same element) molecules are zero

The rest you have to figure out by subtracting or adding to achieve whatever charge the compound bears. 

eg. H2O
H is group 1, so H = +1, there are 2 of them
O must balance the charge so, O=-2

HCl
H=+1, Cl=-1

MgSO4,
you have to know that SO4^2- is a polyatomic ion, treat that as it's own separate thing:
O=-2
Total contribution of O=-2(4) = -8
                                           ^4 oxygen atoms 

Charge on ion=-2, so S has to fulfil the rest which is 6, so S=+6

back to MgSO4, so we treat SO4 as entity and it bears a -2 charge,
Mg therefore has to be +2 to balance the charges.

Try some:

NH4+
NO2
N2O
PCL3
CuBr2