Check an Answer Please ? - See Reply
\[MnO^- + 8H^+ 5e^1 \rightarrow Mn ^{2+} + 4H _{2} O\] \[NO _{3}^ {-} + 3H ^{+} 2e ^{-} \rightarrow HNO _{2} + H _{2}O\] Balancing them of reaction MnO4- with HNO2 Then calculating Gibbs Free Energy
the 5e should be a negative sine btw, the E/V for MNO4 is +1.51 and for HNO2 is +0.94
\[2MnO4^{-} + 16H ^{+} \rightarrow 5NO _{3} ^{-} + 15 H ^{+}\] and n for me was 10
So good so far... which reactions did you donate I and II in order to find right and left?
MnO4 should also be on first equation , sorry first day on this site :/
Then -10 * 96485 * (Not Sure as to the Electrode as cant tell oxidation/reduction) Attempting the I and II now
+0.94 - 1.51 Im presuming is the order or II - I ?
of*
Emmm... I want it to be +1.51 - (+0.94) I: 2 MnO4- + 16 H+ + 10 e- ->2 Mn(2+) + 8 H2O II: 5 NO3- + 15 H+ + 10 e- -> 5 HOH2 + 5 H2O I - II: The reaction for (-II): 5 HOH2 + 5 H2O ->5 NO3- + 15 H+ + 10 e- We then get: 2 MnO4- + 16 H+ + 10 e- + 5 HOH2 + 5 H2O -> 5 NO3- + 15 H+ + 10 e- + 2 Mn(2+) + 8 H2O Remove the things that goes out with each other: 2 MnO4- + 1 H+ + 5 HOH2 + -> 5 NO3- + 2 Mn(2+) + 3 H2O (redox) So it most be: if you are going to calculate Delta G for reaction above. \[\LARGE E _{cell}=E(I)-E(II)\]
I: 2 MnO4- + 16 H+ + 10 e- ->2 Mn(2+) + 8 H2O E=+1.51 II: 5 NO3- + 15 H+ + 10 e- -> 5 NHO2 + 5 H2O E=+0.94 Please check this is the right information; crucial for the result.
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