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Chemistry 20 Online
OpenStudy (anonymous):

What volume of a 1.5 M KOH solution is requred to titrate 30 mL of a 4.5 M H2SO4? H2SO4+2KOH --> K2SO4+2H2O

OpenStudy (joannablackwelder):

You will need twice as many moles of KOH as H2 SO4 for the neutralization reaction to be in molar proportions.

OpenStudy (anonymous):

so what would the volume be? the answers are... a. 158 mL b. 125mL c. 200mL d.45.0 mL e. None of the above

OpenStudy (joannablackwelder):

Do you know how to find the moles of H2SO4 you have? (I wont just give you the answer. It is against policy)

OpenStudy (anonymous):

isnt the moles oh H2SO4 given in the question? 4.5? @JoannaBlackwelder

OpenStudy (joannablackwelder):

No that is the molarity (M). Molarity is in moles/Liter

OpenStudy (anonymous):

Im not really sure how to start it off @JoannaBlackwelder

OpenStudy (joannablackwelder):

Ok. Since you have 30 mL of 4.5 M H2SO4 (that is 4.5 mol H2SO4/ Liter), convert 30 mL to L.

OpenStudy (joannablackwelder):

Then take the number of liters you have and convert it to moles of H2SO4 by multiplying by the molarity. This cancels out liters and leaves you with moles.

OpenStudy (joannablackwelder):

Does that make sense so far?

OpenStudy (anonymous):

so 4.5=.03/x which is .0067

OpenStudy (joannablackwelder):

No, 0.03 L *(4.5 mol/1 L) = 0.135 mol

OpenStudy (joannablackwelder):

It is like converting units.

OpenStudy (anonymous):

ok i understand so whats next

OpenStudy (joannablackwelder):

We can see from the reaction that you need 2 moles of KOH for every 1 mol H2SO4 for the reaction to be at stoichiometric ratios.

OpenStudy (joannablackwelder):

So, 0.135 mol H2SO4 *(2 mol KOH/1 mol H2SO4) =

OpenStudy (anonymous):

.27

OpenStudy (joannablackwelder):

0.27 moles of KOH needed to completely neutralize.

OpenStudy (joannablackwelder):

Right. Do you understand that a titration is a neutralization reaction?

OpenStudy (anonymous):

yes

OpenStudy (joannablackwelder):

Great! So, now can you calculate the volume of KOH (for 1.5 M KOH)?

OpenStudy (anonymous):

.27/1.5?

OpenStudy (joannablackwelder):

Yup :)

OpenStudy (anonymous):

so would the answer be none of the above a. 158 mL b. 125mL c. 200mL d.45.0 mL e. None of the above

OpenStudy (anonymous):

because it would be 180mL

OpenStudy (joannablackwelder):

Yes.

OpenStudy (joannablackwelder):

Correct.

OpenStudy (anonymous):

thank you so much

OpenStudy (joannablackwelder):

No worries

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