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Chemistry 19 Online
zarkam21:

Okay so I am just having trouble with what element this would be?

zarkam21:

Vocaloid:

|dw:1538532034499:dw| should be ar-senic (this website will filter it out if you don't put the dash) it has a full d-block see what you can get from this

zarkam21:

Could you explain this to me I don't get it. Like how I would find the element I know how to do electron configuration though

Vocaloid:

start from hydrogen (row 1) go down to the 4th row (starts with potassium K) group 5A is the 5th column (ignoring the transition metals) which is the column starting with nitrogen

Vocaloid:

this is kind of confusing but there are two numbering systems for groups |dw:1538532364152:dw|

zarkam21:

C?

zarkam21:

Okay so I just googled it and the answer is a .... But, how is it the d value.

Vocaloid:

notice how Ars-enic comes after a full d block so you would expect d10

zarkam21:

Isnt there an empty space going across the d block

zarkam21:

but its empty... does it still count as d10

zarkam21:

even if there aren't any elements

Vocaloid:

empty? the electrons from Sc to Zn are full

Vocaloid:

|dw:1538532708081:dw|

zarkam21:

Oh okay I see.

zarkam21:

Vocaloid:

yeah that should be it the only other possibility would be 7A but let's try 17 for now

zarkam21:

It worked

zarkam21:

zarkam21:

Sodium

Vocaloid:

that's a good guess but sodium is considered an alkali metal |dw:1538533859032:dw| the only nonmetal in the list is phosphorus

zarkam21:

anything above the zigzag?

Vocaloid:

yes

zarkam21:

zarkam21:

Did I match it correctly

Vocaloid:

you need to switch P3+ and P3- and Mg2+ and Mg2- if there are more electrons than protons the overall charge will be negative

zarkam21:

Vocaloid:

pay attention to the group # and position on the ptable. elements toward the left side generally make positive ions and elements towards the right side generally make negative ions K is in group 1 so it gets a +1 charge Mg and Ba are in group 2 so they get a 2+ charge S and O are in group 6A so they need 2 electrons to get the full 8 valance electrons, so they'll take 2 extra electrons to get -2 charge Al is always +3 (you just need to memorize this) N needs 3 electrons --> -3 charge I only needs 1 electron --> -1 charge

zarkam21:

In the ground-state electron configuration of Fe3+, how many unpaired electrons are present?

zarkam21:

4?

zarkam21:

I got [Ar]4s^0 2d^5

zarkam21:

so would it be 4 or 5 because the 4s there isn't any paired and then for 2d5 there is one that is unpaired?

Vocaloid:

each of the 5 electrons in the 2d subshell gets its own orbital, so 5 unpaired

zarkam21:

oh right. but what about the 4s^0

zarkam21:

would they still be paired even with the zero

Vocaloid:

4s^0 means no electrons are in the s orbital so they're not available for pairing

zarkam21:

oh got it

zarkam21:

Build the orbital diagram for the ion most likely formed by phosphorus.

zarkam21:

I drew this

zarkam21:

Vocaloid:

hm not quite Phosphorus wants to attain the same electron config. as the next highest noble gas which is Argon going from Neon to Argon we have [Ne] 3s2 3p6

zarkam21:

oh okay so the answer is [Ne]3s2 3p6

zarkam21:

But wouldnt it be the noble gas before that?

zarkam21:

like the one before p is Ne

Vocaloid:

right, so the previous noble gas is Ne so we'd use Ne instead of helium

zarkam21:

oh right

zarkam21:

I just inputted it wrong. I did orginally do 2p but i guess it didnt show up

Vocaloid:

the d-block should be empty as well

zarkam21:

but it says an ion formed by phosphorous it would be the same right

zarkam21:

so no 3d

Vocaloid:

right

Vocaloid:

it should be the same configuration as Argon

zarkam21:

[Ar]3d^10

zarkam21:

because it would condense down to Ar

Vocaloid:

it still needs to start with Neon

zarkam21:

idk why its condensing down

Vocaloid:

so phosphorus wants to match the higher noble gas (Argon) the configuration of Argon is 1s2 2s2 2p6 3s2 3p6 which is equivalent to [Ne] 3s2 3p6

zarkam21:

zarkam21:

Oh 3p^6 :S

Vocaloid:

why is the 2p orbital above the others it should be between 2s and 3s

zarkam21:

I got [Ne] 3s2 3p6 now

zarkam21:

Is that right

Vocaloid:

the configuration is right, idk what's going on in your orbital diagram

zarkam21:

zarkam21:

Fixed it

zarkam21:

Ugh it says its wrong:/

Vocaloid:

you need to switch 3s and 2p on the orbital diagram if the configuration itself is wrong idk

zarkam21:

wait so which comes first

zarkam21:

2p?

Vocaloid:

1s2 2s2 2p6 3s2 3p6 2p comes before 3s

zarkam21:

Vocaloid:

iirc phosphorus should be larger than sulfur since it's closer to the left side of the ptable otherwise i think it's good

zarkam21:

Vocaloid:

almost, for the last one Se is the bigger one (further down the group and further left on the ptable) Fluorine will pretty much be smaller than everything

zarkam21:

it says its wrong

zarkam21:

You filled in 2 of 4 blanks incorrectly. Note that Sn and I both reside in period 5 of the periodic table (belonging to different groups). Consider the trend of atomic radius as you move right across a period.

zarkam21:

this is what it says

Vocaloid:

huh

zarkam21:

it syas its wrong and then gave me that^ explanation

Vocaloid:

oh duh, the further right you go the smaller the atoms are >_> so Sn will be greater than I

zarkam21:

and then cr is greater than w?

Vocaloid:

hm, no, W should be bigger

zarkam21:

okay then one more that they are saying is wrong

zarkam21:

oh ge?

zarkam21:

is bigger?

Vocaloid:

just a hunch but they might want "not predictable" for Ge vs Po :S

zarkam21:

okay so we got Sn , W, np, and f

zarkam21:

it says one blank is wrong

Vocaloid:

Se is bigger than F

Vocaloid:

\(\color{#0cbb34}{\text{Originally Posted by}}\) @Vocaloid almost, for the last one Se is the bigger one (further down the group and further left on the ptable) Fluorine will pretty much be smaller than everything \(\color{#0cbb34}{\text{End of Quote}}\)

zarkam21:

zarkam21:

Got that one.. For this this is the radius size

zarkam21:

So would it be the same concept

zarkam21:

Rb,Ca,,S,Si,F

zarkam21:

Thats what I put

Vocaloid:

Silicon is bigger than sulfur (it's closer to the left side) Rb,Ca,,Si, S,F

zarkam21:

zarkam21:

C

Vocaloid:

hm, close but not quite, smaller atoms mean more charge, so Cl should have a larger ENC (effective nuclear charge) than P

zarkam21:

a

zarkam21:

So then a right

Vocaloid:

yeah that's what i got too

zarkam21:

zarkam21:

Ge,Cs,In,Se?

Vocaloid:

|dw:1538538277806:dw| hm not quite, since it wants high to low ionization energy try going from the top right to the bottom left corner of the ptable

zarkam21:

,In,Se, Ge, Cs?

Vocaloid:

almost Se is the most towards the upper right going straight left gives us Ge then In, then Cs at the bottom

zarkam21:

Vocaloid:

yikes you need to draw out the orbital diagrams, and if there are unpaired electrons it's paramagnetic, if all the electrons are paired its diamagnetic

zarkam21:

zarkam21:

5 mins ahh

Vocaloid:

uh going from right to left F, O, N, B, Na, Li?

Vocaloid:

there may be some wonky stuff going on with O and N though

Vocaloid:

actually wait, switch the N and O, there's a full subshell on N which makes the energy higher

zarkam21:

Which of the following trends is indirectly proportional to effective nuclear charge, Zeff?

zarkam21:

ionic energy welectron affinity atomic size all the answeres are correct?

Vocaloid:

atomic radii (just have to memorize this)

Vocaloid:

or atomic size i gues

zarkam21:

Of Ca or Sr, the element with the higher first ionization energy is

zarkam21:

Ca?

Vocaloid:

yes

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