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Chemistry 21 Online
OpenStudy (anonymous):

Help please...thanks..

OpenStudy (anonymous):

http://screencast.com/t/t9GRMlxXf

OpenStudy (anonymous):

@Callisto @Preetha @cwrw238

OpenStudy (callisto):

Is it B?

OpenStudy (anonymous):

yeah but how?

OpenStudy (cwrw238):

yes

OpenStudy (cwrw238):

i wasn't sure if it was B or D - i had to check some notes!

OpenStudy (callisto):

Rate is the highest at the beginning.. Since the concentration of the reactants is the highest - more no. of effective collision -> higher rate

OpenStudy (cwrw238):

yup

OpenStudy (callisto):

When the reaction proceeds, the less the reactants are present, the slower the reaction is, and the less of the rate.

OpenStudy (anonymous):

but what about c, the rate increases gradually and decreases or become constant

OpenStudy (callisto):

No... that's the graph for concentration of products formed :|

OpenStudy (callisto):

Remember the rate is the highest at the beginning of the reaction. It can't be 0?!

OpenStudy (anonymous):

why cannt it be 0, coz its strting from 0.. i mean the rate

OpenStudy (callisto):

Good question. That doesn't make sense to me though... When you take a look at the graph for concentration of products. Draw a tangent to the curve at t=0. Slope of tangent = rate of equation Is it equal to 0?

OpenStudy (anonymous):

yup...okay thnks

OpenStudy (callisto):

Huh?!

OpenStudy (anonymous):

i mean i understand, rather it wont be 0 :)

OpenStudy (callisto):

I think Kryten is going to give a better explanation :)

OpenStudy (anonymous):

rate is only 0 at time 0!!! if you look at any other time than 0 reaction begins, so when time begins to flow reaction begins and at the beginning rate is extremely high cause of excess of reactant which is trying to achieve equilibrium, and as other reactant which is in shortage is depleated reaction slows down, and there are also kinetics involved cause the less of the other reactant you have you must either increase mixing of solution so molecules can come closer to react...

OpenStudy (anonymous):

and then finally reaction completes, so the rate of reaction becomes 0

OpenStudy (anonymous):

yes

OpenStudy (anonymous):

that is why kinetics is important, it isnt enough to have apropreate temperature and pressure if you have molecules far apart so they cant react

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