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If 603 mol of octane combusts, what volume of carbon dioxide is produced at 28.0 °C and 0.995 atm?
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\[2C8H18+25O2\rightarrow16CO2+18H2O\]
The ratio of octane to carbon dioxide is 2:16 = 1:8. Therefore 603 mol of octane produces 4824 mol of carbon dioxide. Now use PV = nRT: (0.995)V = (4824)(0.08206)(301) V ~ 120 000 L
It should be noted however @matt101's answer is theoretical, NOT actual. In the real-world you don't even get close to 100% efficiency. :-) I would express as a less than or equal to, just in case.
Absolutely correct @agentx5 - I did a double take when I got 120k L for exactly that reason :)
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