1 mole of HCl (g) + 0.5Mole O2(g) are mixed and allowed to attain equillibrium : 4HCl(g) + O2(g) <-----> 2Cl2(g) + 2H2O(g) at 400C Equillibrium pressure =1atm 0.39mole of Cl2 is formed calculate Kp?
@Yahoo! have u got the last question?????????
Yup..
then y u didn't gave me the medal:(.......lol and let solve it together:) r u??????
oh..i really forgot abt that..) i will give u then..) wait
yup:) now first write Kp for it
but first of all i did nt understand wat it really meant by ::: 1 mole of HCl (g) + 0.5Mole O2(g) are mixed and allowed to attain equillibrium : 4HCl(g) + O2(g) <-----> 2Cl2(g) + 2H2O(g)
4HCl(g) + O2(g) <-----> 2Cl2(g) + 2H2O(g) this is given the standard equation of reaction which tell that 4 moles of HCl react with 1 mole but you have 1mole of HCl and 0.5 mole of O2 that is one is in excess present or we can say the other one is in limiting:)
but it says we have 0.39 moles of Cl2
go with step by step that cl2 help in calculating dissociation so first tell me which one is limiting and which one is in excess????
O2 is excess
4 HCl react with 1 O2 So 0.5 O2 react with 4/1 * 0.5 = 2 Moles of Hcl but we have only 1 mole
right so we always solve whole equation taking the limiting reagent:) now write how many moles are of CL2 are formed?????
4 Hcl --- > 2 Cl2 i Hcl ----> 2/4 * 1 = 0.5 Mole Cl2
but how many moles are formed???????
0.39
so write the no. of moles of each one at the initial of reaction and at the equillibrium taking dissociation constant a:)
Did nt get u..)
1 mole HCl react with 0.25 Mole of O2to give 0.5Mole of Cl2
But we have 0.5 Moles of O2 means 0.25Mole remian unreacted
in last question i wrote at t=0 and t=equlibrium i want u to wrote this:)
Intial 1 0.5 0.39
nope
1 0.5 (0.39 why)
@Yahoo! 0.39 is after the dissociation at initial no reaction takes place so 1 0.5 nothing more:)
1 0.5 0
@Aperogalics
ya now it is correct now write its equilibrium one:)
1-a 0.5 -a 2a
nope you are not taking moles in consideration 1-a 0.25+1/4(0.25-a) 1/2(a)
Hm..hm...yes... is 1/2 (a) = 0.39 ??
yup get a=?
@Yahoo!
\[\frac{ 1a }{ 2 } = 0.39\] \[a = 0.78\]
now write Kp
thxxx.)
it means now you can do it...........:)
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