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How would you calculate the Zeff of Ti? Would the 4s2 electrons be included because those electrons come before the 3d ones of the actual shape
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No. As soon as they're occupied, the 3d orbitals sink below the 4s. That's why the first electrons you lose when you ionize Ti would actually be the 4s electrons. Ti+2 is [Ar]3d2 not [Ar]4s2.
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