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Why does vinegar dissolve in water but oil does not? Vinegar is nonpolar like water, but oil is polar. Vinegar is a pure substance, but oil is already a mixture. Vinegar is polar like water, but oil is nonpolar. Vinegar is a mixture, but oil is a pure substance like water.
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Like dissolves like.
Vinegar is polar like water, but oil is nonpolar. The reason for this is because, if it dissolves in water it is mostly polar.
Vinegar is also 94-95% water and 5-6% acetic acid.
hope this helped!
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