Chemistry
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OpenStudy (yrelhan4):
how do you decide strength of a nucleophile?
13 years ago
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OpenStudy (yrelhan4):
@abb0t
13 years ago
OpenStudy (yrelhan4):
@DLS
13 years ago
OpenStudy (dls):
The larger the size,the stronger is the nucleophile,for example I-
13 years ago
OpenStudy (yrelhan4):
ch3-, nh2-, oh-, f- .. arrange?
13 years ago
OpenStudy (dls):
Try drawing structures of all of them
13 years ago
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OpenStudy (yrelhan4):
usse kya hoga?
13 years ago
OpenStudy (dls):
pata nahi :p
13 years ago
OpenStudy (dls):
NH2-.OH-,F-
13 years ago
OpenStudy (dls):
idk about CH3-
13 years ago
OpenStudy (dls):
ill tell you tomorrow,a better answer indeed.
13 years ago
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OpenStudy (yrelhan4):
okay. explain to me the whole concept. mai bhul chuka hun. :/
13 years ago
OpenStudy (dls):
(Y)
13 years ago
OpenStudy (yrelhan4):
@shubhamsrg
13 years ago
OpenStudy (yrelhan4):
tune batana tha mujhe ye? :/ @DLS
13 years ago
OpenStudy (dls):
kal exam kal pakka :P
13 years ago
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OpenStudy (yrelhan4):
hmm. ok.
13 years ago
OpenStudy (shubhamsrg):
conjugate acid likh ke dekho ?
13 years ago
OpenStudy (yrelhan4):
ch4, nh3, h2o, hf.....
13 years ago
OpenStudy (shubhamsrg):
stronger conjugate acid--> weaker base
13 years ago
OpenStudy (yrelhan4):
hmm. hf>h20>nh3>ch4 ?
13 years ago
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OpenStudy (yrelhan4):
h2o*
13 years ago
OpenStudy (yrelhan4):
acidic strength.
13 years ago
OpenStudy (shubhamsrg):
nh3 is thw strongest base among all isnt it ?
13 years ago
OpenStudy (yrelhan4):
pta nhi. kyun? lone pair?
13 years ago
OpenStudy (shubhamsrg):
yep..all ammonia compounds are very strong lewis bases because of lone pair and size
13 years ago
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OpenStudy (shubhamsrg):
not very strong, just lewis bases.
13 years ago
OpenStudy (yrelhan4):
nucleophilicity directly proportional to basic strength na?
13 years ago
OpenStudy (shubhamsrg):
ha
13 years ago
OpenStudy (yrelhan4):
ha? haha or han? :O
13 years ago
OpenStudy (shubhamsrg):
haha.
han
:P
13 years ago
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OpenStudy (yrelhan4):
i just checked the answer
ch3-> nh2-> oh-> f-
??
13 years ago
OpenStudy (shubhamsrg):
ohh,, ch4 stronger base hota hai nh3 se ?
13 years ago
OpenStudy (yrelhan4):
i dont know. yahi hoga phir.
13 years ago
OpenStudy (shubhamsrg):
ohh,, sahi to hai
13 years ago
OpenStudy (shubhamsrg):
order acid strength ka hoga
hf>h2o>ch4>nh3
13 years ago
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OpenStudy (shubhamsrg):
ohh
nahi :P
13 years ago
OpenStudy (yrelhan4):
wait. ch4 and ch3- are both stronger bases than nh3 and nh2-?
13 years ago
OpenStudy (shubhamsrg):
arre yaar kitna confusion hai! :P
so sorry :/
13 years ago
OpenStudy (shubhamsrg):
ch3- stronger base hai nh2- se
hmm, to
ch4 weaker acid hai nh3 se
hence
ch4 stronger base hai nh3 se
yepo
13 years ago
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OpenStudy (yrelhan4):
hmm. samajh gya.
but...
why is ch3- stronger base than nh2-? :P
13 years ago
OpenStudy (shubhamsrg):
-ve charge aa jata hai less electro-ve element pe shayd isliye ?
13 years ago
OpenStudy (yrelhan4):
hmm. sahi hai. (y)
13 years ago
OpenStudy (yrelhan4):
another question.
ch3o-, oh-,pho-, aco- nucleophilicity?
13 years ago
OpenStudy (yrelhan4):
@shubhamsrg
13 years ago
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OpenStudy (shubhamsrg):
ch3oh , h2o,phoh,ac0h
hmm..
13 years ago
OpenStudy (shubhamsrg):
whats your guesS?
13 years ago
OpenStudy (yrelhan4):
acidic charcater..
acoh>phoh. so the basicity should be pho->aco- . i got this right.
h20>ch3oh +I effect of ch3oh. so the basicity should be oh->ch3o- but this is wrong..
13 years ago
OpenStudy (shubhamsrg):
alcohols are acidic ins't it ?
13 years ago
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OpenStudy (shubhamsrg):
exception? below in the comments , they say it is more acidic!
13 years ago
OpenStudy (yrelhan4):
ch3oh>h2o
but in general alcohols are less acidic than water.
13 years ago
OpenStudy (shubhamsrg):
hmm
13 years ago