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Chemistry 8 Online
OpenStudy (anonymous):

If it requires 48.3 milliliters of 0.55 molar nitric acid to neutralize 15.0 milliliters of barium hydroxide, solve for the molarity of the barium hydroxide solution. Show all of the work used to solve this problem. Unbalanced equation: Ba(OH)2 + HNO3 Ba(NO3)2 + H2O

OpenStudy (anonymous):

@aaronq @abb0t

OpenStudy (aaronq):

Do you know how each one would dissociate? Ba(OH)2 ->? HNO3 ->?

OpenStudy (anonymous):

no not at all

OpenStudy (aaronq):

lol well i guess you don't need to know for this problem, do you care to know?

OpenStudy (anonymous):

if you think it will help yes if not its ok :)

OpenStudy (aaronq):

wait you do need to know this.. you basically need to know the charges of each ion.. Barium would be a divalent cation .. that is, it would carry a +2 charge, I'm sure you know hydroxide has a -1 charge: so it dissociates like this: Ba(OH)2 -> Ba2+ + 2OH- and nitric acid like this: HNO3 -> NO3- + H+ good? for the question you need to find how many moles of nitric acid you used using Molarity = moles of solute/Liters of solution plug stuff in (48.3 milliliters of 0.55 molar nitric acid) then when you know how many moles you used (neutralized) NOW notice that in a neutralization reaction OH- + H+ -> H2O since you produce 2 times OH for every mole of Ba(OH)2 .. you need to multiply the number of moles you got by 2... use the same equation, plug in the moles you got from the multiplication and the volume to find the molarity: molarity= moles/L

OpenStudy (anonymous):

so the answer is what?

OpenStudy (aaronq):

what you calculate?

OpenStudy (anonymous):

i dont even know how to set up the equation

OpenStudy (anonymous):

@seiga

OpenStudy (aaronq):

if you read what i typed you will

OpenStudy (anonymous):

0.55/48.3?

OpenStudy (aaronq):

molar means molarity a measure of concentration

OpenStudy (aaronq):

and you need to convert mL to L, since that's how molarity is defined

OpenStudy (anonymous):

how do i get millileters to L do i times 48.3 times 10 or 100?

OpenStudy (aaronq):

1 L = 1000 mL 1 mL = 0.001 L

OpenStudy (aaronq):

lol what grade are you in?

OpenStudy (anonymous):

10th so 48.3 ml is 0483 l right?

OpenStudy (aaronq):

0.0483

OpenStudy (anonymous):

* 0.0483

OpenStudy (anonymous):

ok so 0.55/0.0483?

OpenStudy (aaronq):

nope 0.55 is the molarity (M) Molarity= moles/ L of solution

OpenStudy (anonymous):

so what do i do then?

OpenStudy (anonymous):

0.55 = x / 0.0483?

OpenStudy (aaronq):

yep, find the moles of base (OH-) you neutralized

OpenStudy (anonymous):

so 0.55 x 0.0483 = 0.026565

OpenStudy (aaronq):

now since Ba(OH)2 gives 2 OH- per molecule multiply that number by 2

OpenStudy (anonymous):

0.026565 x 2 =0.05313

OpenStudy (aaronq):

so you have 0.05313 moles and 15.0 millilitres now use the same formula, plug in and solve for molarity: Molarity = moles / L of solution don't forget to convert

OpenStudy (aaronq):

units mL to L

OpenStudy (anonymous):

15 milileters = 0.015 l right and 0.05323 / 0.015 = 3.542

OpenStudy (aaronq):

wait pellet, you were supposed to divide the number of moles by 2, not multiply, sorry dude

OpenStudy (aaronq):

so 0.55 x 0.0483 = 0.026565 divide by 2 then plug into M=moles/L equation

OpenStudy (anonymous):

ok so 0.026565 / 2 = 0.0132825 15 milileters = 0.015 l right and 0.0132825 / 0.015 =0.8855

OpenStudy (aaronq):

yep thats right

OpenStudy (anonymous):

thanks a lot

OpenStudy (aaronq):

no prob dude

OpenStudy (aaronq):

this stuff is really not hard, you shouldn't be scared of the math. just try stuff

OpenStudy (anonymous):

ok i think im gonna practise

OpenStudy (aaronq):

do it up

OpenStudy (anonymous):

Ba(OH)2 + 2 HNO3 → Ba(NO3)2 + 2 H2O (48.3 mL) x (0.55 M) x (1/2) / (15.0 mL) = 0.886 M Ba(OH)2

OpenStudy (anonymous):

The first thing to note is that the barium ion is 2+ whereas the nitrate ion is -1. So nitric acid only has one hydrogen ion to donate whereas barium hydroxide has two hydroxyl ions. This means you would need twice as much nitric acid than you might expect: Ba(OH)2 + 2 HNO3. The number of moles of nitric acid is 0.0483 multiplied by 0.55M or 0.0266 moles. Dividing this number of moles by 15 ml or 0.015l gives 1.77M but there are two hydroxides per Barium hydroxide molecule and so the concentration is half or 0.886M. Ba(OH)2+2HNO3−→Ba(NO3)22H2O

OpenStudy (anonymous):

hope this helped.

OpenStudy (anonymous):

....

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