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Chemistry 19 Online
OpenStudy (anonymous):

Balance the the following Redox Equation :

OpenStudy (anonymous):

\[Cr _{2}O _{7}^{-2}+I ^{-} ------> Cr ^{+3} + I _{2}\]

OpenStudy (anonymous):

i know all the steps but still cant understand

OpenStudy (anonymous):

Spliting into 2 Partial Equations

OpenStudy (jfraser):

first step ok

OpenStudy (anonymous):

Reduction:- \[Cr _{2} ^{+12} ---> 2Cr ^{+3}\] Oxidation Number for Cr = 12

OpenStudy (jfraser):

the total might be +12, but there's 2 ions to share the charge, so it's +6 each. You also don't want to split the ion up, keep it as Cr2O7

OpenStudy (anonymous):

Reduction:- \[2I^- --> I_2\]

OpenStudy (anonymous):

sorry it was cr207 ---> 2Cr^+3

OpenStudy (jfraser):

\[Cr_2O_7^{-2} \rightarrow 2Cr^{+3}\]and \[2I^{-1} \rightarrow I_2\]

OpenStudy (anonymous):

Now balancing by adding H+ and H2O

OpenStudy (jfraser):

balance O's first by adding H2O

OpenStudy (jfraser):

then balance H+

OpenStudy (anonymous):

this is the part i need help and there is further more part of electrons balancing

OpenStudy (anonymous):

yes plz explain to me help plzz ...how to balance this by H+ and H2O

OpenStudy (jfraser):

balance O's by adding water then balance the waters by adding H+ then balance charge by adding electrons

OpenStudy (anonymous):

Oh man!!! .....it was so easy ....

OpenStudy (jfraser):

\[Cr_2O_7^{-2} \rightarrow 2Cr^{+3}\] balance Os with water\[Cr_2O_7^{-2} \rightarrow 2Cr^{+3} + 7H_2O\] balance H's with H+\[14H^{+1} + Cr_2O_7^{-2} \rightarrow 2Cr^{+3} + 7H_2O\] balance charge with electrons\[6e^{-1} + 14H^{+1} + Cr_2O_7^{-2} \rightarrow 2Cr^{+3} + 7H_2O\]

OpenStudy (anonymous):

YES this is the part !!! i really suck at this part

OpenStudy (anonymous):

how did u added 6e ?

OpenStudy (jfraser):

in the next-to-bottom equation, the total charge of the reactants is +12. the total charge of all the products is +6. The only way to make those charges EQUAL, is to add 6 units of negative charge to the reactants

OpenStudy (anonymous):

and what about the Reduction equation ?

OpenStudy (jfraser):

the reduction is easier because there's no oxygens or hydrogens to balance. so look at the charges and put electrons where they would balance the charges

OpenStudy (anonymous):

how did u get the total of reactants and total of products ? can u tell me ?

OpenStudy (anonymous):

yeah its easy !! 2e are going to add on right side

OpenStudy (jfraser):

2e- goes on the right side, correct now multiply each half-reaction so that the electrons totally cancel when you add them back together

OpenStudy (anonymous):

In oxidation equation how did u get the total charge of reactants and total charge of products ?

OpenStudy (jfraser):

\[6e^{-1} + 14H^{+1} + Cr_2O_7^{-2} \rightarrow 2Cr^{+3} + 7H_2O\]and \[2I^{-1} \rightarrow I_2 + 2e^{-1}\] don't have the same number of electrons, so multiply the second half-reaction by 3, to make 6 electrons\[6I^{-1} \rightarrow 3I_2 + 6e^{-1}\]now add both half-reactions

OpenStudy (anonymous):

yeah the next step of making electrons equal and then adding them is a piece of cake!!!

OpenStudy (jfraser):

add up the charges of all the reactants, that's the total charge

OpenStudy (anonymous):

what are the charges ? plz i need help only in this ELECTRON adding part

OpenStudy (jfraser):

the H+ ions each have a charge of +1, and there are 14 of them the Cr2O7 has a charge of -2, and there's only 1 of them add +14 and -2 together, and you get +12

OpenStudy (anonymous):

And what is the total charge of this \[2Cr^{+3} + 7H_2O\]

OpenStudy (anonymous):

@JFraser ??

OpenStudy (jfraser):

each Cr ion has a charge of +3, and there are 2 of them...

OpenStudy (anonymous):

i am solving a basic equation right now : \[Cr(OH)_3 --> CrO^-4\] How to Balance by adding OH- and H2O ??

OpenStudy (anonymous):

u said first balance O's by adding H2O ........

OpenStudy (anonymous):

but this is difficult

OpenStudy (anonymous):

hello u there ??

OpenStudy (jfraser):

i'm checking your formulas, hang on

OpenStudy (anonymous):

what happened ??

OpenStudy (jfraser):

balancing in basic solutions isn't that much different from acidic solutions, but there are no H+ ions left over once the reactions are balanced

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