I'll become a fan of anyone who can explain this. How would I answer the following: What is the pH of .5 M NaF? the Ka of HF is 4.5e-4.
pH = -log\([H^+]\)
p = P - x H+ y.
what equation is that?
ill give you a hint: when you put NaF in water it will dissociate into Na+ and F-, some of the F- will steal H's from water making OH- in the process F- + H2O <-> HF + OH- the Ka given is for the dissociation of HF into H+ and F- HF <-> H+ + F- Ka = [H+][F-]/[HF]
what would I do next?
you have to use the Kb value for HF and set up an equilibrium expression of this equation: F- + H2O <-> HF + OH-
ps. Kw=Ka*Kb
So eventually I got the Kb to be 2.2e-11
If I take the -log of that and then subtract that value from 14, is that the pH?
@aaronq
you have to find OH- from the equilibrium expression you set up
Kb does not go into -log[H+]
can you show me how?
so pH does not equal pKa?
nope, pH is related to the hydronium concentration, pKa is the point where half of the acid is in protonated and half in deprotonated forms
F- + H2O <-> HF + OH- Kb=products/reactants
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