I'll become a fan of anyone who can explain this.
How would I answer the following:
What is the pH of .5 M NaF? the Ka of HF is 4.5e-4.
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OpenStudy (abb0t):
pH = -log\([H^+]\)
OpenStudy (anonymous):
p = P - x H+ y.
OpenStudy (anonymous):
what equation is that?
OpenStudy (aaronq):
ill give you a hint:
when you put NaF in water it will dissociate into Na+ and F-, some of the F- will steal H's from water making OH- in the process
F- + H2O <-> HF + OH-
the Ka given is for the dissociation of HF into H+ and F-
HF <-> H+ + F-
Ka = [H+][F-]/[HF]
OpenStudy (anonymous):
what would I do next?
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OpenStudy (aaronq):
you have to use the Kb value for HF and set up an equilibrium expression of this equation: F- + H2O <-> HF + OH-
OpenStudy (aaronq):
ps. Kw=Ka*Kb
OpenStudy (anonymous):
So eventually I got the Kb to be 2.2e-11
OpenStudy (anonymous):
If I take the -log of that and then subtract that value from 14, is that the pH?
OpenStudy (anonymous):
@aaronq
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OpenStudy (aaronq):
you have to find OH- from the equilibrium expression you set up
OpenStudy (aaronq):
Kb does not go into -log[H+]
OpenStudy (anonymous):
can you show me how?
OpenStudy (anonymous):
so pH does not equal pKa?
OpenStudy (aaronq):
nope, pH is related to the hydronium concentration, pKa is the point where half of the acid is in protonated and half in deprotonated forms
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