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Chemistry 7 Online
OpenStudy (anonymous):

What is the bond angle in the ClO2- ion?

OpenStudy (anonymous):

I believe.. it is bent( molecular geometry) with 109.5 bond angle because of the two lone pairs on Cl..So it would be tetrahedral for the electron geometry..

OpenStudy (anonymous):

Why would it be 109.5? Why not 120? o.O

OpenStudy (anonymous):

@rere401

OpenStudy (anonymous):

This worksheet helped me out with this.... http://ezquer.ro/?p=335

OpenStudy (anonymous):

Thanks but all I see is <<109. Doesn't that mean less than 109? (Sorry, not really good at this)

OpenStudy (anonymous):

No worries. Okay first, you draw the lewis dot structure....you then see how there is two lone pairs on the Cl..this shows that it's tetrahedral for the base geometry but since there's 2 lone pairs that alters the bond angles. ...and I could be wrong. But that sheet helped me through chem 101. I should of told you it was <<109.5 before.

OpenStudy (abb0t):

It's very similar to water, except that there are \(\pi\)-bonds involved in stead of \(\sigma\)

OpenStudy (anonymous):

oooooh ok. I was reviewing my material and came up with 104.5. Is that plausible?

OpenStudy (abb0t):

Well, this is the structure: |dw:1368596311331:dw|

OpenStudy (abb0t):

unlike water, there are double bonds rather than single bonds. and double bonds are shorter.

OpenStudy (anonymous):

That can't be the structure because it's not fulfilling the octet rule.

OpenStudy (abb0t):

period 3 elements don't have to follow the octet rule.

OpenStudy (anonymous):

I'm pretty sure they do follow the octet rule. (except Hydrogen)

OpenStudy (abb0t):

I mean, you COULD draw it as a resonance structure if it makes you feel more comfortable :) |dw:1368596787395:dw|

OpenStudy (anonymous):

|dw:1368596854189:dw| sorry it's crappy, but this is what it should look like

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