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Chemistry 13 Online
OpenStudy (anonymous):

Which energy-level change shown in the diagram below emits electromagnetic radiation with the longest wavelength? a) an electron moving from 4 to 5 b) an electron moving from 5 to 2 c) an electron moving from 6 to 1 d) an electron moving from 2 to 1

OpenStudy (anonymous):

OpenStudy (anonymous):

@aaronq Would you please help me again? Thanks! Hehe

OpenStudy (aaronq):

"emitting" means that it's going from a higher level to a lower level. eg. 6 to 5 wavelength is tricky because you'd imagine that longer wavelengths mean more energetic, right? but it's actually the opposite. longer wavelengths = less energy shorter wavelengths = more energy so i'll rephrase the question: Which energy-level change shown in the diagram below emits electromagnetic radiation with the least energy photon?

OpenStudy (aaronq):

least energy = least distance transited

OpenStudy (anonymous):

Would it then be 5 to 2? It is quite clear according to this chart. the one I received as a handout has the distance between 2 to 1 and 5 to 2 to be equal...

OpenStudy (aaronq):

yeah, thats the right answer, the only two possibilities would be b) an electron moving from 5 to 2 c) an electron moving from 6 to 1 since the others are absorbing, not emitting photons.

OpenStudy (anonymous):

Oh I see. Thanks. Could I ask you one more question? (without having to make another separate question)

OpenStudy (aaronq):

sure, what is it?

OpenStudy (anonymous):

Which molecule is not pyramidal? a) PH3 b) CO3 2- c) AsH3 d) ClO3 -

OpenStudy (aaronq):

sorry i was re-reading the first question and i noticed that option d) 2 to 1, was also a viable option. But the diagram shows that it's a longer distance. (the answer is still 5 to 2). Now addressing the other question.. you have to draw them according to VSPER theory

OpenStudy (aaronq):

Otherwise, there is no easy way to see, unless by memory

OpenStudy (aaronq):

have you heard of VSPER?

OpenStudy (anonymous):

Yes I have.

OpenStudy (aaronq):

okay, awesome. Just do that

OpenStudy (anonymous):

It is CO3 2-? I just want to make sure because I'm not very good at drawing them...

OpenStudy (aaronq):

yes, indeed it is.

OpenStudy (anonymous):

Thanks so much!!!! :D

OpenStudy (aaronq):

no problem dude !

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