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Chemistry 9 Online
OpenStudy (anonymous):

heisenberg uncertanity principle

OpenStudy (aaronq):

what about it?

OpenStudy (frostbite):

Wondering about the same thing, but I'm just a slave so here we go: \[\huge \Delta \Omega _{1} \Delta \Omega _{2} \ge \frac{ 1 }{ 2 } \left| \langle \left[ \hat{\Omega}_{1}, \hat{\Omega}_{2} \right] \rangle \right|\]

OpenStudy (abb0t):

To someone who isn't familiar with quantum mechanics, let alone chemistry in High school, will not understand that. I dont even understand that.

OpenStudy (chmvijay):

it says Both position and momentum of electron cannot be determined simultaneously :) if u find one accurately then other will have uncertain value (NOT real ) :)

OpenStudy (frostbite):

I explain it even more then. The general uncertain principle is what I wrote. Heisenberg just past the special case with momentum and position. So the uncertainty for momentum and position most be: \[\large \Delta p ~ \Delta q \ge \frac{ 1 }{ 2 } \left| \langle \left[ \hat{x}, \hat{p} \right] \rangle \right|\] Delta p is the uncertainty of linear momentum and Delta q is the uncertainty of position. We now evaluate commutator of the position and linear momentum operators: \[\large \hat{x} ~\hat{p _{x}} \Psi = x \times \frac{ \hbar }{ i } \frac{ d \Psi }{ dx }\] \[\large \hat{p _{x}} ~ \hat{x} ~ \Psi = \frac{ \hbar }{ i }\frac{ d }{ dx }x \Psi = \frac{ \hbar }{ i }\left( \Psi + x\frac{ d \Psi }{ dx } \right)\] The commutator become: \[\large \left[ \hat{x} ,\hat{p _{x}} \right] =\hat{x} ~\hat{p _{x}} - \hat{p _{x}} \hat{x}\] \[\large \left( \hat{x} ~\hat{p _{x}} - \hat{p _{x}} \hat{x} \right) \Psi=\frac{ \hbar }{ i }\left( x \frac{ d \Psi }{ dx } \right)- \frac{ \hbar }{ i }\left( \Psi+x \frac{ d \Psi }{ dx } \right)= i \hbar \Psi\] So we now got: \[\large \Delta p ~ \Delta q \ge \frac{ 1 }{ 2 } \left| i \hbar \right|\] We take the modulus of the complex number and get: \[\large \Delta p ~ \Delta q \ge \frac{ 1 }{ 2 }\hbar\] The expression above is known as the Heisenberg uncertainty principle.

OpenStudy (frostbite):

So what does this mean? We simply use the equation to tell us: Lets say we know a particles position with complete certainty (Delta p = 0) the only way the Heisenberg uncertainty principle can be satisfied then is to set Delta q = infinity. (meaning complete uncertainty)

OpenStudy (aaronq):

what does the accent circonflexe (for lack of mathematical notation knowledge) mean?

OpenStudy (abb0t):

what the funk does any of this mean?!

OpenStudy (frostbite):

The accent circonflexe means "operator" of the observable (postural III)

OpenStudy (abb0t):

OpenStudy (aaronq):

hahah what does the operator do in this case? what's postural III? lol

OpenStudy (aaronq):

hahaha simmer down, kids, simmer down.

OpenStudy (abb0t):

<^>\(^2\)

OpenStudy (abb0t):

I only vaguely remember this from quantum, but I dont remember the formula being that confusing.

OpenStudy (frostbite):

Right well now when I got the latex right I can begin writing: Postulate III states that for each observable property \(\Omega \) there is a corresponding operator \(\hat{\Omega} \) built from the position and linear momentum operator, which I have summarized below: \[\large \hat{x}=x \times\] \[\large \hat{p _{x}}=\frac{ \hbar }{ i }\frac{ d }{ dx }\] To take an example would be to take the well known hamiltonian operator \(\hat{H}\) which has the observable property energy (kinetic energy + potential energy) \(E\). Therefor the Schrödinger equation: \[\hat{H} \Psi=E \Psi\] In general terms, the eigenvalue equation: \[\large \sf \left[ operator ~ for ~ the ~ observable ~ \Omega \right] \Psi=\left[ value ~of ~the ~observable ~ \Omega \right] \times \Psi\] The expected value of an operator is given by the equation: \[\large \langle \Omega \rangle = \int\limits_{}^{} \Psi ^{*} ~ \hat{\Omega} \Psi ~ d \tau\] \(\Psi^*\) is the complex conjugated wavefunction, as the expected value is for a normalized wavefunction. The uncertainty principle build among others on complementary observables \[\large \hat{\Omega}_{1}\hat{\Omega}_{2} \Psi \neq \hat{\Omega}_{2}\hat{\Omega}_{1} \Psi\] When the expression above is true we say two operators do not commute, while two operators that commute follow: \[\large \left[ \hat{\Omega}_{1},\hat{\Omega}_{2} \right]=\hat{\Omega}_{1}\hat{\Omega}_{2} -\hat{\Omega}_{2}\hat{\Omega}_{1} =0\] \(\left[ \hat{\Omega}_{1},\hat{\Omega}_{2} \right]\) I called the commutator. So you could in fact rewrite postulate III as: For every observable property \(\Omega\) there is a corresponding operator \(\hat{\Omega}\) built from the position and linear momentum operators that ensure the commutator for position and linear momentum is true and given by: \[\large \left[ \hat{x},\hat{p _{x}} \right]=i \hbar\] Thanks Abb0t for the latex advise! You are the man.

OpenStudy (frostbite):

The uncertainties are defined as the root mean square form their mean values: \[\large \Delta p=\left( \langle p ^{2} \rangle - \langle p \rangle ^{2} \right)^{1/2}\] \[\large \Delta q=\left( \langle q ^{2} \rangle - \langle q \rangle ^{2} \right)^{1/2}\]

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