How is the electrode potential of a galvanic cell determined?I need the equation....
@thomaster
What?
??? No one?
You mean you need the reaction equation? For example for the Daniell-element?
yah....
Well I just write some stuff then:¨ Lets consider the Daniell-element (a galvanic cell) We can write it as a cell-diagram: \[\Large \sf Zn(s)lZn ^{2+}(aq)l l Cu ^{2+}(aq)l Cu(s)\] As half cells we get: \[\Large \sf Zn ^{2+}(aq) + 2e ^{-} \to Zn(s)\] \[\Large \sf Cu ^{2+}(aq)+2e _{-} \to Cu(s)\] Cell potential: Right cell minus left cell: \[\Large \sf Zn(s)+ Cu ^{2+}(aq) \to Zn ^{2+}(aq)+Cu(s)\]
thanks.
In general: In a galvanic cell the cathode has a higher potential than the anode: the species undergoing reduction, withdraws electrons from its electrode, so leaving a relative positive charge on it (corresponding to a high potential).
Wait a sec: You are going to determine electrode potential. Stupid me. We use Nernst equation: \[\Large E=E ^{\Theta}-\frac{ RT }{ zF }\ln \left( \frac{ \left[ \sf red \right] }{ \left[ \sf ox \right] } \right)\]
ow.lmao its all good:) lol thnks:)
Where \(E^{\Theta}\) is the standard electron potential.
electrode*
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