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Chemistry 13 Online
OpenStudy (adamconner):

question is attached. Please Help! Fan and Medal!!

OpenStudy (adamconner):

OpenStudy (aaronq):

so, the 2 peaks observed are 44 amu and 42 amu, the % abundance of 42 is about twice that of 44. so, \(A_{42}= 100\%\; and\; A_{44}=50\%\;\rightarrow A_{42}=\dfrac{2}{3}\; and \;A_{44}=\dfrac{1}{3}\) we know that: \(A_{average\;atomic\;weight} = 40.5929 amu = A_{42}*A_{42}\%+A_{44}*A_{44}\%\) But, \(A_{44}*(\dfrac{2}{3})+A_{42}*(\dfrac{1}{3})=42.6667 amu\) So the calculated and observed average atomic values are not the same. Can you take it from here?

OpenStudy (adamconner):

first of all how did u get A_42 is 2/3 and A_44 is 1/3??

OpenStudy (aaronq):

I used the height of the peaks which is their relative abundance. for example, if you have A = 100% and B=50%, in total of 150 %. In terms of absolute abundance A=100/150=2/3 B=50/150=1/3

OpenStudy (aaronq):

btw, i just noticed i wrote "\(A_{44}∗(2/3)+A_{42}∗(13)\)=42.6667amu", wrong. I switched the abundance around, BUT when i plugged into the calc i did it right. it should read: " \(A_{42}∗(\dfrac{2}{3})+A_{44}∗(\dfrac{1}{3})\)=42.6667 amu "

OpenStudy (adamconner):

ok, now after that what do i need to do??

OpenStudy (aaronq):

It says in the question, "Sketch a best guess for what the spectrum should be".

OpenStudy (adamconner):

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