Question

What is the difference between molarity and osmolarity?

Answer 1

the osmole (osmol) is a non-SI unit of measurement that defines the number of moles of a chemical compound that contribute to a solution's osmotic pressure. The term comes from the phenomenon of osmosis, and is typically used for osmotically-active solutions. For example, a solution of 1 mol/L NaCl corresponds to an osmolarity of 2 osmol/L. The NaCl salt particle dissociates fully in water to become two separate particles: an Na+ ion and a Cl- ion. Therefore, each mole of NaCl becomes two osmoles in solution. Similarly, a solution of 1 mol/L CaCl2, gives a solution of 3 osmol/L (Ca2+ and 2 Cl-).

A strict definition of an osmole is the amount of osmotically active particles that when dissolved in 22.4 L of solvent at 0 degrees celsius exerts an osmotic pressure of 1 atmosphere. This is equivalent to the observation that 1 mole of a perfect gas occupying a volume of 22.4 L exerts a pressure of 1 atmosphere.

1 osmole = 1 mole of osmotically active particles = o(n)(C),

where o is the osmotic coefficient, n the number of particles resulting from dissociation of each molecule in solution and C the concentration of each molecule in mol/kg of water.

Answer 2

molarity = moles solute/1 L
osmolarity = (moles solute * # of ions of dissociated) / 1L

Answer 3

yes