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what minimum concentration of Na2SO4 is required to cause the precipitation of the cation that precipitates first. (The cation is Ba+). consider that the solution is 1.1*10^-2 M Ba2+ and 1.8*10^-2 M Ca2+
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Do you have the Ksp of BaSO4 and CaSO4?
\[\left[ Na_2SO_4 \right] = \left[ SO_4^{2-} \right] = \frac{K_{sp}(BaSO_4)}{[Ba^{2+}]}\]
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