why is the equation of first law of thermodynamics diff in chem and phy .
only the signs are diff .in phy it is work done by the system and in chem it is work done on system
You've just said it: (English) physics text books and chemistry books use different conventions for signs of work. There is no such change of convention in French or German textbooks: http://fr.wikipedia.org/wiki/Premier_principe_de_la_thermodynamique
It doesnt matter....in physics and chemistry and even in biology 1st law of thermodynamics is same. the difference is the system that ur working with. in physics its a physical system and in chemistry its chemical system. If u r in detail, then u can find all r same
no ther is nothing like different conventions in phy work since it is work done by sym is denoted as -w in chem work since it is work done on sym is denoted as +w
in physics workdone on system is +w in chemistry workdone by system is -w
"in phy work since it is work done by sym is denoted as -w in chem work since it is work done on sym is denoted as +w" Well choosing if you take into account work done BY or ON the system to write a formula, is what you call a convention, don't you?
-w means u hve to supply energy to do that work lack of energy +w stands for excess energy of the system which converted into work
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