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Chemistry 14 Online
OpenStudy (anonymous):

I'm quite sure about this one, but anyone who can verify this? Am I correct in stating that the ZnFe2O4 spinel (ZnO:Fe2O3) is not ferrimagnetic due to the fact that Zn2+ is a diamagnetic ion (completely filled d shell).

OpenStudy (anonymous):

you are correct

OpenStudy (aaronq):

i don't see why Fe(III) wouldn't be paramagnetic, I'm not sure what kind of geometry this has though.

OpenStudy (anonymous):

hi

OpenStudy (anonymous):

Fe3+ is paramagnetic. The question is wether the compound can be ferrimagnetic, ie have alternating planes (zn2+ and fe3+) with opposite spins, but not equal. I am saying that the zn2+ plane cant have any net spin cause zn2+ is diamagnetic.

OpenStudy (aaronq):

sounds good

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