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question on chemical kinetics....... it is said that molecularity of the slowest step of a complex reaction itself is the order of the overall reaction.......but molecularity is always an integer,while order can be integer or a fraction.....if order itself is ultimately the molecularity .....then how come order be a fraction sometimes???
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Molecularity is mostly related to limited reactant concept. see the principle of chemical science lectures 8.111 OCW course. Order tell the reaction rate, how fast the reaction is ?..
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