Chemistry
9 Online
OpenStudy (anonymous):
A certain first-order reaction has a rate constant of 2.80×10−2s−1 at 15∘C. What is the value of k at 62∘C if Ea = 112kJ/mol ?
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OpenStudy (aaronq):
use the two-point arrhenius equation: \(ln\dfrac{k_1}{k_2}=\dfrac{E_a}{R}*(\dfrac{1}{T_2}-\dfrac{1}{T_1})\)
OpenStudy (anonymous):
I have tried that and it doesnt get the right answer :(
OpenStudy (aaronq):
you used Kelvin?
OpenStudy (anonymous):
yes and i changed kj to J
OpenStudy (aaronq):
let me see what i get
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OpenStudy (aaronq):
are you getting 19.82?
OpenStudy (anonymous):
no -6.5
OpenStudy (anonymous):
do you have to do something with the k1 too?
OpenStudy (aaronq):
yeah, you have to fill all the parameters except what you're looking for
OpenStudy (anonymous):
cause if you do then i got .00004
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OpenStudy (aaronq):
hm i got 19.82
OpenStudy (anonymous):
so 112000/8.314 * ((1/335)-(1/288)) = -6.56
OpenStudy (aaronq):
yeah, then \(ln(\dfrac{2.80×10^{−2}}{k_2})=-6.56\)
OpenStudy (anonymous):
oh i see you take the reciprocal ok i got your answer now
OpenStudy (aaronq):
sweet, that should be correct
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OpenStudy (anonymous):
but the answer is supossed to be 2.3
OpenStudy (aaronq):
really? thats odd. is this a reliable source?
OpenStudy (anonymous):
mastering chemistry...online text software
OpenStudy (anonymous):
oh no we were right!! I just answered the wrong question lol. Thanks a lot it is right!!
OpenStudy (aaronq):
ohh ok, cool cool
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OpenStudy (aaronq):
no prob