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OpenStudy (jfraser):
in order to do work and expand, a gas must "use" some of its energy to push the walls of the container and do the actual expansion. The negative sign simply implies the loss of energy by the system in doing the work.
OpenStudy (anonymous):
ok thnx then what is the significance of the formula \[W=PdV\]? acc to this workdone should be positive since dV is positive fo expansion
OpenStudy (anonymous):
its just sign convention
in chemistry it is negative
in physics it is positive
OpenStudy (anonymous):
ok but why ? is there nothing behind it?
OpenStudy (anonymous):
i think concept should be same
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OpenStudy (anonymous):
no buddy again its just sign convention
decided by some scientists
OpenStudy (anonymous):
ok thnx
OpenStudy (anonymous):
no problem
exams in one month
wish me luck
OpenStudy (anonymous):
gud luck
OpenStudy (anonymous):
thanks
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OpenStudy (anonymous):
wlcm
OpenStudy (aaronq):
the formula is \(w=\underbrace{\color{red}-}P_{Ext}\Delta V\)
negative sign