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Chemistry 7 Online
OpenStudy (anonymous):

Please explain step by step????

OpenStudy (anonymous):

1. A mountain biker goes for a ride in the desert. The air temperature is 21°C at the start of the ride, but the temperature in the desert will reach a peak of 51°C. The tires on the bike hold 15.6 L of nitrogen gas at a starting pressure of 249 kPa. The tires will burst when the internal pressure (Pb) reaches 269 kPa. Answer the following questions and show your work. • How many moles of nitrogen gas are in each tire? • What will the tire pressure be at the peak temperature in the desert? • Will the tires burst at the peak temperature? Explain. • To what pressure should the tire pressure be reduced before starting the ride to avoid bursting of the tires in the desert heat? (Assume no significant change in tire volume.) Answer:

OpenStudy (aaronq):

How many moles of nitrogen gas are in each tire? use PV=nRT with on set of conditions (e.g. at the start of the bike ride), solve for moles, n.

OpenStudy (aaronq):

one set*

OpenStudy (anonymous):

how do you find that

OpenStudy (aaronq):

find what?

OpenStudy (anonymous):

using the formual i dont understand @aaronq

OpenStudy (aaronq):

can you identify the parameters you need to plug into the formula? P = pressure V=volume n=moles R=constant can be found here: http://en.wikipedia.org/wiki/Gas_constant (needs to match your pressure and volume units) T= temp in Kelvin; T in K = 273.15 + T in Celsius

OpenStudy (anonymous):

but i dont understand how to slove for n

OpenStudy (aaronq):

you would solve it algebraically, you first need to determine what you're plugging into the formula.

OpenStudy (anonymous):

got that. but what goes over what

OpenStudy (aaronq):

rearrange the formula algebraically.

OpenStudy (aaronq):

ab=cd \(\rightarrow a=\dfrac{cd}{b}\)

OpenStudy (anonymous):

so would it be n= pv over rt (on bottom)

OpenStudy (aaronq):

yes

OpenStudy (anonymous):

is p=249kpa v=269kpa r=15.6 t=51c ?

OpenStudy (anonymous):

im really not sure about that

OpenStudy (aaronq):

please re-read what i posted above. R is to be found on that link, T needs to be in Kelvin, V is volume ("kPa" are units of pressure).

OpenStudy (anonymous):

t=324.15 r= 8.31 v=15.6 p=246kpa is that right

OpenStudy (anonymous):

@aaronq

OpenStudy (aaronq):

almost, you either have to use the other temp given or the other pressure given, because one set is for the start point, the other is when you're in the desert (hotter thus higher pressure).

OpenStudy (anonymous):

so p should be 269

OpenStudy (aaronq):

yeah, that works. now just plug it all in and solve

OpenStudy (anonymous):

is 1.42 the answer ? thats what i got

OpenStudy (aaronq):

yep, thats it

OpenStudy (aaronq):

oh wait, 269 kPa is not the pressure in the desert, it's when the tire will pop. you needed to use the first set of numbers, ill do it for you cuz it's my fault n = [249 kPa*15.6 L]/[(21+273.15)*8.31] = 1.589 moles

OpenStudy (anonymous):

Aw okay thank you :)

OpenStudy (aaronq):

for "What will the tire pressure be at the peak temperature in the desert?" use a modified version of the ideal gas equation: \(\dfrac{P_1}{T_1}=\dfrac{P_2}{T_2}\)

OpenStudy (aaronq):

you can ignore n, R and V, for this part because they are constant throughout the problem.

OpenStudy (anonymous):

so would it be 267kpa over 21 and 246pka over 51?

OpenStudy (aaronq):

nope, then you'd have nothing to solve for. you're looking for the pressure when it's 51 Celsius, so 246 and 21 are on one side and 51 and unknown pressure on the other Remember also that the temp MUST be in Kelvin

OpenStudy (anonymous):

so is it 246 over 294.15 and x over 324.15?

OpenStudy (aaronq):

yes

OpenStudy (anonymous):

is the answer 271.089

OpenStudy (aaronq):

yes it is

OpenStudy (aaronq):

Will the tires burst at the peak temperature? Explain. basically if the pressure is over 269 kPa at that temp, the tires will pop.

OpenStudy (anonymous):

and what about the last one

OpenStudy (aaronq):

now you're using the high temp and pressure just below the bursting temp (below 269 kPa) to find what the pressure should be (not at the desert) so use the same formula with these new numbers

OpenStudy (anonymous):

which formula the first one you gave me?

OpenStudy (anonymous):

and is the high temp 51

OpenStudy (aaronq):

the formula is \(\dfrac{P_1}{T_1}=\dfrac{P_2}{T_2}\) and yes that temp

OpenStudy (anonymous):

im confused what numbers do i use now

OpenStudy (aaronq):

21 on the left, 268.9 kPa and 51 on the right

OpenStudy (aaronq):

remember use Kelvin

OpenStudy (anonymous):

i got 653.042 is that right?

OpenStudy (aaronq):

that can't be right, the pressure should be less than the initial pressure (246 kPa)

OpenStudy (anonymous):

i put 21 over 268.9 and 51 over X

OpenStudy (aaronq):

it's the other way around

OpenStudy (anonymous):

i still got the same thing :/

OpenStudy (aaronq):

did you use Kelvin?

OpenStudy (anonymous):

yes

OpenStudy (aaronq):

weird, i got: (21+273)/268.9= (51+273)/x x=296.338

OpenStudy (anonymous):

ohh okay

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