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Chemistry 2 Online
OpenStudy (anonymous):

A solution is formed by mixing 50.0 mL of 14.6 M NaX with 50.0 mL of 2.7 10-3 M CuNO3. Assume that Cu(I) forms complex ions with X - as follows. Cu+(aq) + X -(aq) equilibrium reaction arrow CuX(aq) K1 = 1.0 ✕ 102 CuX(aq) + X -(aq) equilibrium reaction arrow CuX2-(aq) K2 = 1.0 ✕ 104 CuX2-(aq) + X -(aq) equilibrium reaction arrow CuX32-(aq) K3 = 1.0 ✕ 103 The overall reaction is the following. Cu+(aq) + 3 X -(aq) equilibrium reaction arrow CuX32-(aq) K = 1.0 ✕ 109 Calculate the following concentrations at equilibrium. CuX3 2- CuX2 - CuX

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