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Chemistry 8 Online
OpenStudy (somy):

can anyone explain this to me? In black and white photographic film, light converts silver chloride into metallic silver. After the film has been developed, the unexposed silver chloride is removed by reaction with sodium thiosulphate to produce a ‘fixed’ negative.

OpenStudy (somy):

this is the reaction

OpenStudy (somy):

and the question is What is the function of thiosulphate? the ans is to make the silver ions soluble

OpenStudy (somy):

@Kainui @aaronq can any of you explain this please? i don't get the question, not even the reaction itself.((

OpenStudy (somy):

@chmvijay

OpenStudy (anonymous):

This is the full question, if you require :)

OpenStudy (chmvijay):

can u tell me the oxidation state of [Ag(S2O3)2]^-3 before that the Ag was in oxidation state

OpenStudy (anonymous):

no idea

OpenStudy (anonymous):

lool

OpenStudy (somy):

i think its +1 to +2

OpenStudy (chmvijay):

wait

OpenStudy (chmvijay):

Thiosulfate converts undeveloped silver chloride grains in the film into water-soluble silver thiosulfate complexes that can be removed when the film is washed.for that purpose it is added and in both the case the silver oxidation state remains the same hence its not any oxidation process

OpenStudy (chmvijay):

can u tell now which option is correct ?

OpenStudy (anonymous):

A??

OpenStudy (chmvijay):

bingooo!!! yup if u want still more explanation just watch here Sodium thiosulphate, also spelled "sodium thiosulfate and commonly called "hypo," is the critical component in traditional photographic fixer solutions. Black-and-white photographic paper contains silver halide compounds which react by darkening in the presence of light. During printing, the paper is exposed to light through the photographic negative. Unexposed areas on the paper contain residual silver halides that must be stripped from the paper to prevent slow discoloration or fogging of the photograph over time. Fixers react with the unexposed silver halides and convert them into chemicals that are easily flushed away with water.

OpenStudy (anonymous):

lol

OpenStudy (somy):

sorry im here just a sec

OpenStudy (chmvijay):

its already 1920. seconds :P

OpenStudy (somy):

owh

OpenStudy (somy):

sorry i was away

OpenStudy (somy):

sorry im kinda not getting this, how did u come up with this Thiosulfate converts undeveloped silver chloride grains in the film into water-soluble silver thiosulfate complexes that can be removed when the film is washed.for that purpose it is added and in both the case the silver oxidation state remains the same hence its not any oxidation process

OpenStudy (chmvijay):

see some of AgCl may remain on the plate to remove them u need to make them easily soluble , bcoz the AgCl is not soluble so easily if u wash with sodium thiosulfate these excess AgCl will get solubalized in sodium thiosulfate and makes the plate clean

OpenStudy (somy):

oww i get it now :D thnx @chmvijay

OpenStudy (chmvijay):

thank god atl ast you got it :P

OpenStudy (somy):

yeah lol @chmvijay

OpenStudy (chmvijay):

LOL :P i was just kidding :)have a nice day

OpenStudy (somy):

heh thnxx @chmvijay

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