25cm3 of a solution of O.2M potassium hydroxide reacts with 30cm3 of a solution of nitric acid. What is the concentration of the acid in g dm-3?
Sorry, I'm late!
what does dm stand for? Decimeter?
Yes. Zeta, don't be apologetic.
Ok so just use M1V1 = M2V2 25ml NaOH x 0.2M NaOH = M of HNO3 x 30ml HNO3 M of HNO3 = 0.167 M or grams / mol
grams / Liter, not "mol" lol sorry
so....
1L is just 1meter ^3
so... 0.167 mol / 1meter^3 x (10^3 decimeters / 1 meter^3) = 167 mol/decimeter
*correciton again, the initial answer I got was 0.167 mol / L not "g/mol or g/L" LOl sorry
so it should be 167 mol/decimeter^3
My answer is coming to be 10.5.
Let me rewrite this neatly
Ok so just use M1V1 = M2V2 25ml NaOH x 0.2M NaOH = M of HNO3 x 30ml HNO3 M of HNO3 = 0.167 M or 0.167 mol/L 1L = 1 meter^3 so 0.167 mol / 1 meter^3 x ( [10 decimeter]^3 / 1 meter^3) = 167 mol / decimeter^3
oh you want units of "grams" / decimeter ^3 ok sorry lets set that straight
167 mol HNO3 / 1 decimeter^3 x ( 63 grams HNO3 / 1 mol HNO3) = 10521 grams / decimeter^3. I would like it more if the denominator was in meters^3 (or liters) so that the answer would be 10.521 grams / meters^3
So ya you're right the answer is 10.5 but you can only get that if your denominator is "meters^3" NOT "DECImeter^3" as you had told me
so with everything neatly again Ok so just use M1V1 = M2V2 25ml NaOH x 0.2M NaOH = M of HNO3 x 30ml HNO3 M of HNO3 = 0.167 M or 0.167 mol/L 1L = 1 meter^3 so 0.167 mol / 1 meter^3 x (63 grams HNO3 / 1 mol HNO3) = 10.521 grams / meter^3 of HNO3
First of all, your reaction is the following:\[\rm \color{#C00}1KOH + \color{#C00}1HNO_3 \to \color{#C00}1KNO_3 + \color{#C00}1H_2O\]This tells you that the number of moles of both \(\rm KOH\) and \(\rm HNO_3\) are the same. The question indirectly gives you the number of moles of \(\rm KOH\). It tells you that the molarity of \(\rm KOH\) is 0.2, meaning that the number of moles of \(\rm KOH\) in \(\rm 1000 cm^3\) of solution is 0.2. Here, you have \(\rm 25 cm^3\) so the number of moles of \(\rm KOH\) would be \(\frac{25}{1000} = \frac{1}{40}\). You have the same number of moles for nitric acid (remember why?). So there are \(1/40\) moles of nitric acid which means that its mass is \(1/40 \times (1 + 14 + 48) = 1/40 \times (M_0) = M_0/40 ~\rm grams\). You are given the volume to be \(\rm 30 cm^3\). \(\rm 1 dm^3\) is \(1000 \rm cm^3\), so the volume of this solution in cubic-decimeters would be \(\frac{30}{1000} =\rm \frac{3}{100} dm^3\). Dividing the two, you will get\[\rm conc = \dfrac{M_0/40}{3/100} = \dfrac{100 /40 \times M_0}{3} = \dfrac{2.5}{3} \times 63 = 2.5 \times 21 = 52.5\]
Oh no...
Um, no Zeta, that's wrong
I've already solved it
Yes, that's wrong by a factor of five because I did not take the 0.2 into consideration. The answer would be \(52.5 \times 1/5 = 10.5\)
I think my way is simpler haha
Sure.
I sense some competition here. Anyway, thank you both.
Obviously I know more chem than Zeta haha
We have the same approach though. :) M1V1 = M2V2 is not necessarily true, so I think we must first list down our reaction and compare like I did.
It's definitely true b/c this is a neutralization reaction so the moles of acid must equal the moles of base. Another way or writing moles is Molarity x Volume (b/c it comes from the equation Molarity = moles / Volume). So moles acid = moles base is the same thing as Macid x Vacid = Mbase x Vbase
But ya you can see the 1:1 mole relationship via the equation too
\[\rm 2NaOH + H_2CO_3 \to N_2CO_3 + 2 NaOH\]
this isn't a neutralization (which occurs between strong acid and strong base) but instead a weak acid - strong base titration
Well, fair enough.
lol
Though looking at it from a stoichiometric point of view, it may not be necessary that the coefficients are always the same. So I guess you're right... darn!!! I give up.
lmao
We're both right, just you did it the long way I did it the short way
Alright I'm out, PEACE!
That's a subjective way to think about it. I made it one long reply, plus I showed all steps of my work. So yeah.
this is my entire final reply: 25ml NaOH x 0.2M NaOH = M of HNO3 x 30ml HNO3 M of HNO3 = 0.167 M or 0.167 mol/L 1L = 1 meter^3 so 0.167 mol / 1 meter^3 x (63 grams HNO3 / 1 mol HNO3) = 10.521 grams / meter^3 of HNO3
that's it
I'm pretty sure this is objectively shorter than your reply lol
ok.
Sorry im just bored lol
\[\rm moles = \dfrac{25}{1000}\times \dfrac{1}{5} = \dfrac{1}{200}\]\[\rm mass = \dfrac{63}{200} g\]\[\rm volume = \dfrac{30}{1000} dm^3\]\[\rm conc = mass/volume = 10.5 gdm^{-3}\]
You win brah lol. I'm out now. peace
Join our real-time social learning platform and learn together with your friends!