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Chemistry 22 Online
OpenStudy (anonymous):

3 Ag2S + 2 Al(s) = Al2S3 + 6 Ag(s) Is this a galvanic cell or electrolytic cell? Explain your answer.

OpenStudy (anonymous):

i do know that galvanic cell = the negative electrode, where oxidation occurs

OpenStudy (australopithecus):

So you didnt learn anything about electromotive force? http://chemistry.about.com/library/weekly/aa082003a.htm

OpenStudy (anonymous):

nope. i take this online course thing and the material is really vague...

OpenStudy (anonymous):

so its a galvanic cell

OpenStudy (australopithecus):

http://chemwiki.ucdavis.edu/Analytical_Chemistry/Electrochemistry/Basics_of_Electrochemistry Check out the section cell potential, essentially you use electromotive force to determine which way the reaction goes spontaneously if it is galvanic cell the reaction happens spontaneously, if it is an electrolytic cell then the reaction is not spontaneous

OpenStudy (australopithecus):

you need to apply electricity to it to cause it to go forward

OpenStudy (anonymous):

ah no. its not spontaneous so the equation is actually an electrolytic cell

OpenStudy (australopithecus):

well if you know that then you know the answer

OpenStudy (anonymous):

3 Ag2S + 2 Al(s) = Al2S3 + 6 Ag(s) is electrolytic

OpenStudy (australopithecus):

you can tell what is the cathode and what the anode is by what is being reduced and what is being oxidized https://upload.wikimedia.org/wikipedia/commons/2/2f/Galvanic_cell_with_no_cation_flow.png you can see from this diagram that the negative end the anode is losing electrons so it is being oxidized you can see that the cathode is gaining electrons so it is being Reduced

OpenStudy (anonymous):

in the equation, ag is oxidized

OpenStudy (australopithecus):

It has been awhile since I have thought about this stuff but it is actually pretty interesting if you ever want to isolate certain metals like sodium which is a pretty fun metal as it reacts violently with water

OpenStudy (australopithecus):

just write the half reactions, I'm pretty sure that Al is being oxidized

OpenStudy (anonymous):

Oxidation Reaction: Al(s) —> Al(3+) + 3e- Reduction Reaction: Ag(+) + e(-) —> Ag(s)

OpenStudy (anonymous):

you're right

OpenStudy (anonymous):

wait so is it galvanic...? I'm confused

OpenStudy (australopithecus):

You cant tell which it is unless you look at the electromotive force

OpenStudy (australopithecus):

Electromotive force of cell = Electromotive force (cathode)-Electromotive foce (Anode) Pretty sure if it is negative the reaction is not spontanous thus it would be electrolytic cell and galvanic if the other way around

OpenStudy (australopithecus):

You find your electromotive forces for each individual half reaction here, https://en.wikipedia.org/wiki/Standard_electrode_potential_%28data_page%29

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