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Chemistry 12 Online
OpenStudy (anonymous):

What concentration of ClO3– results when 637 mL of 0.583 M AgClO3 is mixed with 633 mL of 0.265 M Mn(ClO3)2?

OpenStudy (australopithecus):

Molarity = Moles/Litres so, 0.637L of AgClO3 Dissociates into: Ag(ClO3) -> Ag+ + ClO3- Find moles of ClO3- 0.633mL of Mn(ClO3)2 Dissociates into Mn(ClO3)2 -> Mn + 2(ClO3-) Find moles of ClO3- To find final concentration: Volume of solution 1 + volume of solution 2 = New volume of solution Moles of ClO3 in Solution 1 + Moles of ClO3 in solution 2 = Total moles of ClO3 in solution Sub into, Molarity = Moles/Liters Solve for molarity and you have your answer

OpenStudy (anonymous):

isn't there a concentration formal i could use?

OpenStudy (australopithecus):

Yes, Molarity = moles/liters

OpenStudy (australopithecus):

you need to find the moles for both solutions individual and add their sum then you need to take the volumes of both solutions and add them together and then put them into the formula

OpenStudy (australopithecus):

To find moles you have volume of the original solution and concentration of the original solution sub into that formula and find moles. Then use the dissociation formula I provided to find moles of ClO3-

OpenStudy (australopithecus):

so for the first one, 633 mL = 0.633L and Molarity = 0.583 M thus, 0.583M = x/0.633L solve for x to find moles of AgClo3 in 637 mL at a concentration of 0.583 M

OpenStudy (anonymous):

i mean a formula like m1 * v1= m2*v2

OpenStudy (anonymous):

n ohh okay

OpenStudy (australopithecus):

That is used for dilutions, this isn't necessarily a dilution, if anything we are equilibrating these two concentrations solutions (they will both be in between what they once were)

OpenStudy (anonymous):

so the first x = 0.369

OpenStudy (australopithecus):

right

OpenStudy (australopithecus):

Now look at the formula for disassociation (this is an ionic compound), Ag(ClO3) -> Ag+ + ClO3- To go from moles of AgClO3 to ClO3- you divide the number in front of the compound you are starting with, in this case it is 1 so, 0.369mol/1 Then you multiply that number by the number in front of ClO3-, in this case the number in front of ClO3- is 1, so, (0.369mol/1)*1 I hope you understanding balancing of equations etc

OpenStudy (anonymous):

okay and everything in the equation has a coefficient of 1 in front of the chemical formulas.

OpenStudy (australopithecus):

(0.369mol/1)*1 = moles of ClO3- This is a case where for every 1 mole of AgClO3 for every mole of ClO3- The next solution is not this case but just follow my steps and you will get the right answer

OpenStudy (australopithecus):

This is a case where for every 1 mole of AgClO3 there is 1 mole of ClO3- dissociated

OpenStudy (anonymous):

oh okay n for the next part i got .168 so do add both variable now?

OpenStudy (anonymous):

.369 +.167

OpenStudy (australopithecus):

Nope you made a mistake for calculating the moles in the second solution

OpenStudy (australopithecus):

you skipped a step

OpenStudy (australopithecus):

look at the dissociation of Mn(ClO3)2

OpenStudy (australopithecus):

it isn't 1 to 1

OpenStudy (anonymous):

oh isnt .265mole= x/.633?

OpenStudy (australopithecus):

that is correct but you just have moles of Mn(ClO3)2 at that point

OpenStudy (australopithecus):

you dont have moles of ClO3 in that particular solution

OpenStudy (australopithecus):

look at the dissociation formula for Mn(ClO3)2

OpenStudy (anonymous):

what do you mean by dissociation formula sorry for the dumb question

OpenStudy (australopithecus):

Read through what I posted

OpenStudy (australopithecus):

It is very important you understand what I did for the first solution if you want to do well in chemistry

OpenStudy (australopithecus):

I posted the dissociation formula for it in my first post but you should understand how I got it

OpenStudy (anonymous):

oh i see what your saying i thought ur talking bout a specific formula so it dissociates into Mn^ +2 (ClO3-) right but arent the coeffients still one?

OpenStudy (australopithecus):

then your compound would be MnClO3+ since adding the charges, 2+ + -1 = +1 The actual compound is Mn(ClO3)2 so, Mn 2+ + ClO3- + ClO3- so, 2+ + -1 + -1 = 0 Mn(ClO3)2 ^ this means that there are two molecules of ClO3, hence the brackets with the subscript 2

OpenStudy (anonymous):

so then it .168/2 = .084 * 1= .084? right

OpenStudy (anonymous):

okay thanks

OpenStudy (australopithecus):

Mn(ClO3)2 -> Mn 2+ + 2(ClO3-)

OpenStudy (australopithecus):

so there is a 1 in front of Mn(ClO3)2 and a 2 in front of ClO3-

OpenStudy (australopithecus):

divide by 1 and then multiply by 2

OpenStudy (australopithecus):

to get moles of ClO3-

OpenStudy (australopithecus):

make sure you understand this

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