) A reaction is found to have an activation energy of 38.0 kJ/mol. If the rate constant for this reaction is 1.60 × 102 M-1s-1 at 249 K, what is the rate constant at 436 K? A) 2.38 × 105 M-1s-1 B) 1.26 × 103 M-1s-1 C) 7.94 × 104 M-1s-1 D) 4.20 × 105 M-1s-1 E) 3.80 × 104 M-1s-1 Answer: D
we will use lnk2/k1=( Ea/R)(1/t1-1/t2)
kk 1 sec
ok
Im working in a group preparing for my chemistry exam and my group wants to just praise to you for helping us understand these problems. we have a test on Monday and you made everything so simple and we will pass now lol
Im happy to hear that I could help, and you will all do excellent
kk I got this one
lets do it
1. convert 38.0kj to joules so 38*10^3Joule R=constant 8.3145 2.equation 1.60^2*e^(38Jmole*8.3145)*(249-436) 3. 1.60^2e^(7.87233)=4.20*105
what variable are we solving for so i can mentally see where you are going with the numbers
kk 1 sec
we are solving for k2
working it out to see if i can get the answer
1.) ln(k2/k1)=(Ea/R)(t1-t2) 2.) ln(1.60*10^2/k1)=(38*10^3)(249-436) 3.) ln(1.60*10^2/k1)(=(65.4544) 4 k1(1.60*10^2) =65.4544/ln 5.k1=1.60*10^2*e^65.4544= 4.20*105 Remember when dividing by ln, make it e^
so we were solving for k1 or k2
basically just use algebra rules
okay that makes sense now
okay we have one more which is similar to this one
is it making sense, sorry I am a slow typer
yes the problem we had was getting rid of the ln. we had no clue
also it is easier to fully solve the right side of the equation and just have one number instead of all the equations
then once we do that we can take the e to get rid of the ln and the multiply to get rid of the k1 which leaves us with k2
Basically for this problem, divide the right side with ln (ea*ti-t2) make it say e^value
yes
im going to post the last question that we have for you and that will complete us lol
yes k2 is what you are finding k1=1.60*10^2
kk sounds good, did this problem make sense
at first it didnt because i didnt know what we were looking for and i got lost in all of the different variables but the way you broke it down shows all of the steps i needed.
kk awseome!
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